A New Method of Analyzing Thermogravimetric Data
TLDR
In this paper, a new method of obtaining the kinetic parameters from thermogravimetric curves has been proposed, which is simple and applicable to reactions which can not be analyzed by other methods.Abstract:
A new method of obtaining the kinetic parameters from thermogravimetric curves has been proposed. The method is simple and applicable to reactions which can not be analyzed by other methods. The effect of the heating rate on thermogravimetric curves has been elucidated, and the master curve of the experimental curves at different heating rates has been derived. The applications of the method to the pyrolyses of calcium oxalate and nylon 6 have been shown ; the results are in good agreement with the reported values. The applicability of the method to other types of thermal analyses has been discussed, and the method of the conversion of the data to other conditions of temperature change has been suggested. From these discussions, the definition of the thermal stability of materials has been criticized.read more
Citations
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Reaction mechanisms and multi-scale modelling of lignocellulosic biomass pyrolysis
TL;DR: In this article, the authors describe pyrolysis of lignocellulosic biomass, and the individual reaction mechanisms of cellulose, hemicellulose and lignin are initially described.
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Enhanced Hydrogen Storage Kinetics of LiBH4 in Nanoporous Carbon Scaffolds
TL;DR: In this paper, an enhanced kinetics for hydrogen exchange in LiBH4 incorporated within nanoporous carbon scaffolds are described. And the authors demonstrate that confinement within a porous scaffold host is a promising approach for enhancing hydrogen uptake and release in reversible light-metal complex hydrides.
Journal ArticleDOI
Mechanism and Kinetics of Epoxy-Amine Cure Studied by Differential Scanning Calorimetry
TL;DR: In this paper, an isoconversional kinetic analysis has been applied to nonisothermal DSC data on the cure of an epoxynovolac resin, revealing a dependence of the activation energy (Eα) on conversion (α).
Journal ArticleDOI
Model-free kinetics
TL;DR: In this paper, a model-free kinetic approach is presented in the context of the traditional kinetic description based on the kinetic triplet, A, E, and f(α) or g(α), which is not interpretable in terms of the reaction mechanism and of the vibrational frequency of the activated complex.
Journal ArticleDOI
ICTAC Kinetics Committee recommendations for analysis of multi-step kinetics
Sergey Vyazovkin,Alan K. Burnham,Loïc Favergeon,Nobuyoshi Koga,Elena Moukhina,Luis A. Pérez-Maqueda,Nicolas Sbirrazzuoli +6 more
TL;DR: The present recommendations provide guidance on kinetic analysis of multi-step processes as measured by thermal analysis methods such as thermogravimetry and differential scanning calorimetry.
References
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Journal ArticleDOI
Kinetic Parameters from Thermogravimetric Data
A. W. Coats,J. P. Redfern +1 more
TL;DR: In this article, a thermocouple is used to measure the sample temperature in a Stanton HT-D thermobalance, the bead of which is positioned in or near the sample, depending on crucible design.
Journal ArticleDOI
A New Analysis of Thermogravimetric Traces.
H. H. Horowitz,Gershon. Metzger +1 more
Journal ArticleDOI
The Application of Thermoanalytical Techniques to Reaction Kinetics: The Thermogravimetric Evaluation of the Kinetics of the Decomposition of Calcium Oxalate Monohydrate
Eli S. Freeman,Benjamin Carroll +1 more
Journal ArticleDOI
Kinetic analysis of thermogravimetric data
TL;DR: The kinetic analysis of the thermogram, by use of either its exact equation or a more convenient approximation formula, is straightforward in cases of volatilization via simple kinetics as mentioned in this paper.
Journal ArticleDOI
Estimating isothermal life from thermogravimetric data
TL;DR: In this paper, the authors presented a method for estimating equivalent isothermal life from thermogravimetric data and for estimating the apparent activation energy for volatilization even though the nature of the kinetic process is unknown.
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