A New Method of Analyzing Thermogravimetric Data
TLDR
In this paper, a new method of obtaining the kinetic parameters from thermogravimetric curves has been proposed, which is simple and applicable to reactions which can not be analyzed by other methods.Abstract:
A new method of obtaining the kinetic parameters from thermogravimetric curves has been proposed. The method is simple and applicable to reactions which can not be analyzed by other methods. The effect of the heating rate on thermogravimetric curves has been elucidated, and the master curve of the experimental curves at different heating rates has been derived. The applications of the method to the pyrolyses of calcium oxalate and nylon 6 have been shown ; the results are in good agreement with the reported values. The applicability of the method to other types of thermal analyses has been discussed, and the method of the conversion of the data to other conditions of temperature change has been suggested. From these discussions, the definition of the thermal stability of materials has been criticized.read more
Citations
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Desilication of ferrierite zeolite for porosity generation and improved effectiveness in polyethylene pyrolysis
TL;DR: In this article, commercial H-ferrierite (Si/Al = 29) with the characteristic plate-like morphology was used as starting material for catalytic pyrolysis of low-density polyethylene.
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Thermal degradation of typical plastics under high heating rate conditions by TG-FTIR: Pyrolysis behaviors and kinetic analysis
TL;DR: In this paper, low-density polyethylene (LDPE), polypropylene (PP) and polyvinyl chloride (PVC) were studied under high heating rate conditions to investigate pyrolysis behaviors and find the most suitable kinetic reaction mechanisms.
Journal ArticleDOI
Methods for kinetic analysis of thermally stimulated processes
TL;DR: Several methods are known for the evaluation of the main kinetic parameters related to a thermoluminescence (TL) curve, namely the activation energy, the preexponential factor and the kinetic order as discussed by the authors.
Journal ArticleDOI
Pyrolysis and kinetic analyses of Camel grass (Cymbopogon schoenanthus) for bioenergy.
Muhammad Aamer Mehmood,Guangbin Ye,Huibo Luo,Chen-Guang Liu,Sana Malik,Ifrah Afzal,Jianren Xu,Muhammad Sajjad Ahmad +7 more
TL;DR: The Gibb's free energy and High Heating Value have shown the considerable bioenergy potential of this low-cost biomass.
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Computational aspects of kinetic analysis.: Part E: The ICTAC Kinetics Project—numerical techniques and kinetics of solid state processes
TL;DR: In this paper, the authors present the kinetic results computed for a hypothetical simulated process and experimental data for the thermal decomposition of calcium carbonate and ammonium perchlorate. But the results show that model-fitting techniques are successful in correctly describing the decomposition when assuming multi-step kinetic models, and the results indicate that proper consideration of the experimental conditions at which the reaction has been investigated should be taken into account for a correct interpretation of kinetic data of solid-gas reactions.
References
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Journal ArticleDOI
Kinetic Parameters from Thermogravimetric Data
A. W. Coats,J. P. Redfern +1 more
TL;DR: In this article, a thermocouple is used to measure the sample temperature in a Stanton HT-D thermobalance, the bead of which is positioned in or near the sample, depending on crucible design.
Journal ArticleDOI
A New Analysis of Thermogravimetric Traces.
H. H. Horowitz,Gershon. Metzger +1 more
Journal ArticleDOI
The Application of Thermoanalytical Techniques to Reaction Kinetics: The Thermogravimetric Evaluation of the Kinetics of the Decomposition of Calcium Oxalate Monohydrate
Eli S. Freeman,Benjamin Carroll +1 more
Journal ArticleDOI
Kinetic analysis of thermogravimetric data
TL;DR: The kinetic analysis of the thermogram, by use of either its exact equation or a more convenient approximation formula, is straightforward in cases of volatilization via simple kinetics as mentioned in this paper.
Journal ArticleDOI
Estimating isothermal life from thermogravimetric data
TL;DR: In this paper, the authors presented a method for estimating equivalent isothermal life from thermogravimetric data and for estimating the apparent activation energy for volatilization even though the nature of the kinetic process is unknown.
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