A New Method of Analyzing Thermogravimetric Data
TLDR
In this paper, a new method of obtaining the kinetic parameters from thermogravimetric curves has been proposed, which is simple and applicable to reactions which can not be analyzed by other methods.Abstract:
A new method of obtaining the kinetic parameters from thermogravimetric curves has been proposed. The method is simple and applicable to reactions which can not be analyzed by other methods. The effect of the heating rate on thermogravimetric curves has been elucidated, and the master curve of the experimental curves at different heating rates has been derived. The applications of the method to the pyrolyses of calcium oxalate and nylon 6 have been shown ; the results are in good agreement with the reported values. The applicability of the method to other types of thermal analyses has been discussed, and the method of the conversion of the data to other conditions of temperature change has been suggested. From these discussions, the definition of the thermal stability of materials has been criticized.read more
Citations
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Flammability assessment of fire-retarded Nordic Spruce wood using thermogravimetric analyses and cone calorimetry
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A new iterative linear integral isoconversional method for the determination of the activation energy varying with the conversion degree
Junmeng Cai,Siyu Chen +1 more
TL;DR: A new iterative linear integral isoconversional method for the determination of theactivation energy as a function of the conversion degree has been proposed, which is capable of providing valid values of the activation energy even if the latter strongly varies with the conversiondegree.
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Comparing kinetics and mechanism of adsorption and thermo-oxidative decomposition of Athabasca asphaltenes onto TiO2, ZrO2, and CeO2 nanoparticles
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Increased functional properties and thermal stability of flexible cellulose nanocrystal/ZnO films
TL;DR: Mechanical results demonstrate a high structural integrity of CNC/ZnO as a result of the occurring strong cellulosic inter- and intramolecular interactions within the closely packed CNC network.
Journal ArticleDOI
A kinetic compensation effect established for the thermal decomposition of a solid
Nobuyoshi Koga,Haruhiko Tanaka +1 more
TL;DR: In this article, two causes for the kinetic compensation effect (KCE) were recognized for a given solidstate reaction at various heating rates, one due to any change in the range of reaction and the other due to misestimation of the appropriate rate law.
References
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Journal ArticleDOI
Kinetic Parameters from Thermogravimetric Data
A. W. Coats,J. P. Redfern +1 more
TL;DR: In this article, a thermocouple is used to measure the sample temperature in a Stanton HT-D thermobalance, the bead of which is positioned in or near the sample, depending on crucible design.
Journal ArticleDOI
A New Analysis of Thermogravimetric Traces.
H. H. Horowitz,Gershon. Metzger +1 more
Journal ArticleDOI
The Application of Thermoanalytical Techniques to Reaction Kinetics: The Thermogravimetric Evaluation of the Kinetics of the Decomposition of Calcium Oxalate Monohydrate
Eli S. Freeman,Benjamin Carroll +1 more
Journal ArticleDOI
Kinetic analysis of thermogravimetric data
TL;DR: The kinetic analysis of the thermogram, by use of either its exact equation or a more convenient approximation formula, is straightforward in cases of volatilization via simple kinetics as mentioned in this paper.
Journal ArticleDOI
Estimating isothermal life from thermogravimetric data
TL;DR: In this paper, the authors presented a method for estimating equivalent isothermal life from thermogravimetric data and for estimating the apparent activation energy for volatilization even though the nature of the kinetic process is unknown.
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