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A review of the structure, and fundamental mechanisms and kinetics of the leaching of chalcopyrite.

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TLDR
There is general agreement in the literature that chalcopyrite leaching is significantly affected by solution redox potential with an optimum E(h) range suggesting the participation of leach steps that involve both oxidation and reduction.
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This article is published in Advances in Colloid and Interface Science.The article was published on 2013-09-01. It has received 338 citations till now. The article focuses on the topics: Chalcopyrite & Leaching (metallurgy).

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Citations
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Metal extraction from spent lithium-ion batteries (LIBs) at high pulp density by environmentally friendly bioleaching process

TL;DR: In this article, the authors investigated the bio-leaching of a mixture of LiCoO2-based spent lithium-ion batteries at high pulp density (100g/L) using cost-efficient autotrophic bacteria Acidithiobacillus ferrooxidans.
Journal ArticleDOI

Kinetics and roles of solution and surface species of chalcopyrite dissolution at 650 mV

TL;DR: In this paper, the dissolution rate of chalcopyrite was found to be positively correlated with the activities of Fe3+, as a Fe 3 + 1.54 ( ± 0.07 ), and H+ as a H + 0.13 ( ± 1.05 ).
Journal ArticleDOI

New insights into the surface relaxation and oxidation of chalcopyrite exposed to O2 and H2O: A first-principles DFT study

TL;DR: In this paper, the surface anisotropy of chalcopyrite surfaces was investigated under both dry and aqueous atmospheres through a fundamental density functional theory (DFT) study.
Journal ArticleDOI

A critical review of the passivation and semiconductor mechanisms of chalcopyrite leaching

TL;DR: The idea that chalcopyrite leaching is hindered by a passivation layer is challenged in this paper, where it is shown that in alkaline solutions with a complexing agent there is no passivating effect.
References
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Journal ArticleDOI

Generalized Gradient Approximation Made Simple

TL;DR: A simple derivation of a simple GGA is presented, in which all parameters (other than those in LSD) are fundamental constants, and only general features of the detailed construction underlying the Perdew-Wang 1991 (PW91) GGA are invoked.
BookDOI

Photoelectron spectroscopy : principles and applications

TL;DR: In this paper, the three low-index faces of a Face-Centered Cubic (fcc) Crystal Face were modeled as 3D cubic faces, and a table of binding energies was presented.
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