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AC impedance spectroscopy study of the corrosion behavior of an AZ91 magnesium alloy in 0.1 M sodium sulfate solution

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TLDR
In this paper, the corrosion behavior of an AZ91 magnesium alloy in 0.1 M sodium sulfate solution at the corrosion potential (E-corr) was investigated using electrochemical impedance spectroscopy (EIS), environmental scanning electron microscopy (ESEM), energy dispersive X-ray spectroscopic (EDS), and Xray photo-electron spectrograph (XPS).
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This article is published in Electrochimica Acta.The article was published on 2007-02-15. It has received 179 citations till now. The article focuses on the topics: Corrosion & Dielectric spectroscopy.

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Fundamentals and advances in magnesium alloy corrosion

TL;DR: There remains growing interest in magnesium (Mg) and its alloys, as they are the lightest structural metallic materials Mg alloys have the potential to enable design of lighter engineered systems, including positive implications for reduced energy consumption as mentioned in this paper.
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In vitro degradation and mechanical integrity of calcium-containing magnesium alloys in modified-simulated body fluid

TL;DR: The in vitro study suggests that calcium-containing magnesium alloys to be a promising candidate for their applications in degradable orthopaedic implants, and it is worthwhile to further investigate the in vivo corrosion behaviour of these alloys.
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Influence of pH and chloride ion concentration on the corrosion of Mg alloy ZE41

TL;DR: In this paper, the influence of pH and chloride ion concentration on the corrosion behavior of ZE41 was studied using immersion tests and electrochemical measurements, and it was shown that the fraction of film free surface increases with decreasing bulk pH and with increasing chloride ion concentrations.
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Calculated phase diagrams and the corrosion of die-cast Mg–Al alloys

TL;DR: In this paper, the corrosion of commercial die-cast Mg-Al alloys was elucidated by a study, of the corrosion in 3% NaCl, of (i) high-pressure diecast (HPDC) model Mg alloys, (ii) low-purity Mg, (iii) high purity (HP) Mg and (iv) HP Mg heat treated at 550°C.
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Effect of rare earth element Ce and La on corrosion behavior of AM60 magnesium alloy

TL;DR: In this article, a new AM60-RE (RE = Ce or La) alloy was prepared and its corrosion behavior was evaluated by hydrogen evolution and electrochemical methods, and the corrosion resistance of AM60 alloy improved with addition of RE, and this improvement could attribute to depression of the micro-galvanic couples.
References
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Influence of microstructure on the corrosion of diecast AZ91D

TL;DR: In this paper, the corrosion of die cast AZ91D was studied and related to its microstructure, and it was found that the casting method can influence the corrosion performance by its influence on the alloy microstructures, which is attributed to a combination of higher volume fraction of the beta phase, a more continuous beta phase distribution around finer alpha grains, and lower porosity in the skin layer than in the interior of the die casting.
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Corrosion behaviour of AZ21, AZ501 and AZ91 in sodium chloride

TL;DR: In this article, the corrosion behavior of dual phase alloys was studied in 1 N NaCl at pH 11 by measuring electrochemical polarization curves, electrochemical AC impedance spectroscopy (EIS) and simultaneously measuring the hydrogen evolution rate and the magnesium dissolution rate.
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The anodic dissolution of magnesium in chloride and sulphate solutions

TL;DR: In this article, the electrochemical behavior of magnesium was studied in representative chloride and sulphate solutions including NaCl, Na2SO4, NaOH and their mixed solutions, HCl, and H2SO 4: (1) by measuring electrochemical polarisation curves, (2) by using electrochemical impedance spectroscopy (EIS), and (3) by simultaneous measurement of hydrogen gas evolution and measurement of magnesium dissolution rates using ICPEAS.
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Corrosion of magnesium

TL;DR: Magnesium alloys have high strength/weight ratios, but poor corrosion resistance affects the viability of increased magnesium usage in aerospace and other applications as discussed by the authors, and this review approaches the p...
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Evaluation of microstructural effects on corrosion behaviour of AZ91D magnesium alloy

TL;DR: In this paper, the effect of microconstituents on the corrosion and electrochemical behaviour of AZ91D alloy prepared by die-casting and ingot casting route has been investigated in 3.5% NaCl solution at pH 7.25.
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