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Journal ArticleDOI

Atomic Distributions in Liquid Elements

Carl Christian Gamertsfelder
- 01 Jun 1941 - 
- Vol. 9, Iss: 6, pp 450-457
TLDR
In this article, the effect of temperature change on diffraction patterns of liquid chlorine, tin, indium, zinc, cadmium, aluminum, and lithium was analyzed using Mo Kα radiation and the Fourier analysis of these patterns led to the determination of atomic distribution curves for each element.
Abstract
Monochromatic x‐ray diffraction patterns of liquid chlorine, tin, indium, zinc, cadmium, aluminum, and lithium were obtained, using Mo Kα radiation. The effect of temperature change on the patterns was determined for tin and indium. Fourier analyses of these patterns led to the determination of atomic distribution curves for each element. Each atom in liquid chlorine has one nearest neighbor, which means that chlorine is diatomic in the liquid state. The distribution curves for liquid tin, zinc and aluminum agree very well with the distributions in the corresponding crystals. The distribution curves for indium, cadmium, and lithium do not agree very well with distributions in the corresponding crystals.

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Citations
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Journal ArticleDOI

A theory of the electrical properties of liquid metals II. Polyvalent metals

TL;DR: In this article, the electronic properties of liquid polyvalent metals are discussed in relation to the nearly free-electron model and the optical properties fit a simple Drude formula, with the same density of states as for free electrons.
Journal ArticleDOI

Reference Data for the Density and Viscosity of Liquid Cadmium, Cobalt, Gallium, Indium, Mercury, Silicon, Thallium, and Zinc

TL;DR: In this article, the available experimental data for the density and viscosity of liquid cadmium, cobalt, gallium, indium, mercury, silicon, thallium, and zinc have been critically examined with the intention of establishing both a density and a visosity standard.
Journal ArticleDOI

The radial distribution curves of liquids by diffraction methods

TL;DR: In this paper, a detailed discussion is given of apparatus and experimental methods and the procedure for processing experimental data is described from the polarization and absorption corrections to an estimation of the final radial distribution curve.
Journal ArticleDOI

Structure of Alkali Metals in the Liquid State

TL;DR: In this paper, the atomic distribution curves were computed for all the above cases, and compared with results from x-ray diffraction, and the number of nearest neighbors is, within one half atom, about 9.0 to 9.5 atoms in each case.
References
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Journal ArticleDOI

Die Beugung von Röntgenstrahlen in Flüssigkeiten als Effekt der Molekülanordnung

TL;DR: The Einfuhrung einer Verteilungsfunktion fur die gegenseitige Entfernung der Molekule ermoglicht die Ableitung ein Formel fur die Zerstreuung von Rontgenstrahlen in Flussigkeiten, welche alle Eigentumlich keiten der Beobachtungen gut wiedergibt as mentioned in this paper.
Journal ArticleDOI

Theoretical diffraction patterns corresponding to some simple types of molecular arrangement in liquids

TL;DR: Theoretical diffraction patterns are computed for liquid-arrangements, corresponding to the following structures: A cubic and hexagonal close packed, B body-centered cubic, C simple cubic, D diamond structure as mentioned in this paper.
Journal ArticleDOI

X-Ray Studies of the Molecular Arrangement in Liquids

TL;DR: In this paper, an improved technique has been developed for taking x-ray diffraction photographs of weakly absorbing liquids, including water, heptane, decane, benzene and cyclohexane, and several hitherto unobserved details have been discovered.
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