Journal ArticleDOI
Beyond pristine metal-organic frameworks: Preparation and application of nanostructured, nanosized, and analogous MOFs
TLDR
In this paper, the preparation of MOFs with various nanostructured features (such as hierarchical/hollow pore architectures and defected structure), together with MOF-based composites, analogous MOFs and nanosized MOFs, are discussed systematically.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2018-12-01. It has received 107 citations till now.read more
Citations
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Metal-Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications.
TL;DR: In this article, the recent advances in the design, synthesis, and functional applications of metal-organic frameworks (MOFs) based hierarchically porous materials are summarized, and a comparison of HP-MOFs with traditional porous materials (e.g., zeolite, porous silica, carbons, metal oxides, and polymers) are also indicated.
Journal ArticleDOI
Metal-organic framework-based materials as an emerging platform for advanced electrochemical sensing
TL;DR: In this article, a detailed discussion about the structure-property relationship, and different strategies used for the rational design and controllable synthesis of versatile MOF-based materials based on the specific requirements of the final electrochemical sensing applications are outlined.
Journal ArticleDOI
Metal-Organic Framework-Based Enzyme Biocomposites.
Weibin Liang,Peter Wied,Francesco Carraro,Christopher J. Sumby,Bernd Nidetzky,Chia-Kuang Tsung,Paolo Falcaro,Christian J. Doonan +7 more
TL;DR: A review of the characterization methodologies used for enzyme/MOF-immobilized enzymes can be found in this article, where the authors discuss enzyme protection via encapsulation, pore infiltration and surface adsorption and summarizes strategies to form multicomponent composites.
Journal ArticleDOI
Metal-organic frameworks as photoluminescent biosensing platforms: mechanisms and applications.
TL;DR: In this paper, the authors provided readers with an extensive overview of the design and synthesis of MOF materials for photoluminescence biosensing, including photoelectron transfer (PET), resonance energy transfer (RET), competition absorption (CA), structural transformation (ST), chemical conversion (CC), and quencher detachment (QD).
Journal ArticleDOI
Metal sulfide/MOF-based composites as visible-light-driven photocatalysts for enhanced hydrogen production from water splitting
Yang Liu,Danlian Huang,Min Cheng,Zhifeng Liu,Cui Lai,Chen Zhang,Chengyun Zhou,Weiping Xiong,Lei Qin,Binbin Shao,Qinghua Liang +10 more
TL;DR: In this article, the progress in the design and synthesis of various metal sulfide/MOF-based nanocomposites for applications in photocatalytic H2 production is provided.
References
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Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
Journal ArticleDOI
Reticular synthesis and the design of new materials
Omar M. Yaghi,Michael O'Keeffe,Nathan W. Ockwig,Hee K. Chae,Hee K. Chae,Mohamed Eddaoudi,Jaheon Kim +6 more
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
Journal ArticleDOI
Metal–Organic Framework Materials as Chemical Sensors
Lauren E. Kreno,Kirsty Leong,Omar K. Farha,Mark D. Allendorf,Richard P. Van Duyne,Joseph T. Hupp +5 more
TL;DR: The potential to computationally predict, with good accuracy, affinities of guests for host frameworks points to the prospect of routinely predesigning frameworks to deliver desired properties.
Journal ArticleDOI
Hybrid porous solids: past, present, future
TL;DR: The state-of-the-art on hybrid porous solids, their advantages, their new routes of synthesis, the structural concepts useful for their 'design', aiming at reaching very large pores are presented.
Journal ArticleDOI
A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability.
Jasmina Hafizovic Cavka,Søren Jakobsen,Unni Olsbye,Nathalie Guillou,Carlo Lamberti,Silvia Bordiga,Karl Petter Lillerud +6 more
TL;DR: The Zr-MOFs presented in this work have the toughness needed for industrial applications; decomposition temperature above 500 degrees C and resistance to most chemicals, and they remain crystalline even after exposure to 10 tons/cm2 of external pressure.