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Journal ArticleDOI

Carbon Encapsulated Tin Oxide Nanocomposites: An Efficient Anode for High Performance Sodium-Ion Batteries.

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TLDR
A simple and cost-effective hydrothermal method to prepare carbon coated tin oxide (SnO2) nanostructures as an efficient anode material for NIBs was reported as a function of the solvent used.
Abstract
The major obstacle in realizing sodium (Na)-ion batteries (NIBs) is the absence of suitable negative electrodes. This is because graphite, a commercially well known anode material for lithium-ion batteries, cannot be utilized as an insertion host for Na ions due to its large ionic size. In this study, a simple and cost-effective hydrothermal method to prepare carbon coated tin oxide (SnO2) nanostructures as an efficient anode material for NIBs was reported as a function of the solvent used. A single phase SnO2 resulted for the ethanol solvent, while a blend of SnO and SnO2 resulted for the DI water and ethylene glycol solvents. The elemental mapping in the transmission electron microscopy confirmed the presence of carbon coating on the SnO2 nanoparticles. In cell tests, the anodes of carbon coated SnO2 prepared in ethanol solvent exhibited stable cycling performance and attained a capacity of about 514 mAh g–1 on the first charge. With the help of the conductive carbon coating, the SnO2 delivers more capa...

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Citations
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Journal ArticleDOI

Sodium-ion batteries: present and future

TL;DR: Current research on materials is summarized and discussed and future directions for SIBs are proposed to provide important insights into scientific and practical issues in the development of S IBs.
Journal ArticleDOI

A Review on Design Strategies for Carbon Based Metal Oxides and Sulfides Nanocomposites for High Performance Li and Na Ion Battery Anodes

TL;DR: In this article, the authors present and discuss the development of carbon-based nanocomposite anodes in both Li ion batteries and Na ion batteries, focusing on strategies employed in fabricating such composites, with examples such as yolkshell structure, layered-by-layered structure, and composite comprising one or more carbon matrices.
Journal ArticleDOI

Metal oxide/graphene composite anode materials for sodium-ion batteries

TL;DR: In this article, the authors provide a comprehensive summary of the research development on the low-cost metal oxides/graphene composites (MOs/G) as anode materials for SIBs.
Journal ArticleDOI

Growth of SnO 2 Nanoflowers on N-doped Carbon Nanofibers as Anode for Li- and Na-ion Batteries

TL;DR: The hybrid NC@SnO2 is synthesized through the hydrothermal growth of SnO2 nanoflowers on the surface of N-doped carbon fibers obtained by electrospinning to serve as a conductive network to accelerate electronic transmission along one-dimensional structure effectively.
Journal ArticleDOI

Toward a Stable Sodium Metal Anode in Carbonate Electrolyte: A Compact, Inorganic Alloy Interface

TL;DR: This work adds a small amount of SnCl 2 additive in a common carbonate electrolyte so that the spontaneous reaction between SnCl2 and Na metal enables in situ formation of a Na-Sn alloy layer and a compact NaCl-rich SEI, which can provide an easily scalable and cost-effective approach for developing high-performance Na-metal batteries.
References
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Journal ArticleDOI

Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)

TL;DR: Mise au point comportant des definitions generales et la terminologie, la methodologie utilisee, les procedes experimentaux, les interpretations des donnees d'adsorption, les determinations de l'aire superficielle, and les donnes sur la mesoporosite et la microporosite.
Journal ArticleDOI

Battery materials for ultrafast charging and discharging

TL;DR: It is shown that batteries which obtain high energy density by storing charge in the bulk of a material can also achieve ultrahigh discharge rates, comparable to those of supercapacitors.
Journal ArticleDOI

Na-ion batteries, recent advances and present challenges to become low cost energy storage systems

TL;DR: In this paper, a review of Na-ion battery materials is presented, with the aim of providing a wide view of the systems that have already been explored and a starting point for the new research on this battery technology.
Journal ArticleDOI

Electrochemical and In Situ X‐Ray Diffraction Studies of the Reaction of Lithium with Tin Oxide Composites

TL;DR: In this article, an electrochemical and in situ x-ray diffraction experiments on a variety of tin oxide based compounds; SnO,,,, and glass, as cathodes opposite lithium metal in a rechargeable Li-ion coin cell were conducted.
Journal ArticleDOI

High Capacity Anode Materials for Rechargeable Sodium‐Ion Batteries

TL;DR: In this article, the authors compare the results with those for lithium insertion in graphitic carbon anode materials and demonstrate the presence of similar alkali metal insertion mechanisms in both cases.
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