Journal ArticleDOI
Cobalt–Pincer Complexes in Catalysis
TLDR
In this review the recent progress in (de)hydrogenation, transfer hydrogenation, hydroboration and hydrosilylation as well as dehydrogenative coupling reactions using cobalt-pincer complexes is summarised.Abstract:
Non-noble metal catalysts based on pincer type compounds are of special interest for organometallic chemistry and organic synthesis. Next to iron and manganese, currently cobalt-pincer type complexes are successfully applied in various catalytic reactions. In this review the recent progress in (de)hydrogenation, transfer hydrogenation, hydroboration and hydrosilylation as well as dehydrogenative coupling reactions using cobalt-pincer complexes is summarised.read more
Citations
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Journal ArticleDOI
Strategies and mechanisms of metal-ligand cooperativity in first-row transition metal complex catalysts.
Matthew R. Elsby,R. Tom Baker +1 more
TL;DR: This review encapsulates advances made in metal-ligand cooperation by transition metal bifunctional catalysts over the last ten years, focusing exclusively on first-row transition metals, and highlighting significant contributions to mechanistic understanding.
Journal ArticleDOI
First-Row d-Block Element-Catalyzed Carbon-Boron Bond Formation and Related Processes.
Shubhankar Kumar Bose,Lujia Mao,Laura Kuehn,Udo Radius,Jan Nekvinda,Webster L. Santos,Stephen A. Westcott,Patrick G. Steel,Todd B. Marder +8 more
TL;DR: A review of the state-of-the-art in the use of first-row d-block element-based catalysts for the formation of carbon-boron bonds can be found in this article.
Journal ArticleDOI
Development of a practical non-noble metal catalyst for hydrogenation of N-heteroarenes
TL;DR: In this paper, a simple manganese complex was used in the hydrogenation of N-heteroarenes, without the need for additional ligands, and showed the important role of a concomitantly formed Mn(ii) species and HBr for the hydrogenization of the heterocyclic substrates.
Journal ArticleDOI
Cobalt-Catalyzed Asymmetric Hydrogenation of C=N Bonds Enabled by Assisted Coordination and Nonbonding Interactions.
TL;DR: An efficient cobalt-catalyzed asymmetric hydrogenation of C=N bond has been realized for the first time and has practical applications for the synthesis of several useful chiral nitrogen-containing compounds.
Journal ArticleDOI
Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation.
Sem Raj Tamang,Michael Findlater +1 more
TL;DR: The development of some base metals (Fe, Co, and Ni) in the hydroboration and hydrosilylation reactions is detailed with a brief overview of recent advances in the field.
References
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Journal ArticleDOI
Cyclometalated phosphine-based pincer complexes: Mechanistic insight in catalysis, coordination, and bond activation
Journal ArticleDOI
Highly Active Iron and Cobalt Catalysts for the Polymerization of Ethylene
Journal ArticleDOI
Applications of acceptorless dehydrogenation and related transformations in chemical synthesis.
TL;DR: Acceptorless dehydrogenation and related dehydrogenative coupling reactions have the potential for redirecting synthetic strategies to the use of sustainable resources, devoid of toxic reagents and deleterious side reactions, with no waste generation.
Journal ArticleDOI
Novel olefin polymerization catalysts based on iron and cobalt
George J. P. Britovsek,Vernon C. Gibson,Stuart James Mctavish,Gregory A. Solan,Andrew J. P. White,David J. Williams,Brian Stephen Kimberley,Peter James Maddox +7 more
TL;DR: A new family of olefin polymerization catalysts, derived from iron and cobalt complexes bearing 2,6-bis(imino)pyridyl ligands, was described in this paper.
Journal ArticleDOI
Metal-ligand cooperation by aromatization-dearomatization: a new paradigm in bond activation and "green" catalysis.
TL;DR: A range of novel catalytic reactions that were developed guided by these new modes of metal-ligand cooperation are described, including a unique water splitting process, which involves consecutive thermal liberation of H(2) and light-induced liberation of O(2), using no sacrificial reagents, promoted by a pyridine-based pincer ruthenium complex.
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