Journal ArticleDOI
First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands.
TLDR
This review aims at providing a comprehensive picture of the utilization of functional pincer ligands in first-row transition metal hydrogenation and dehydrogenation catalysis and related synthetic concepts relying on these such as the hydrogen borrowing methodology.Abstract:
The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with respect to “traditional” precious metal catalyzed transformations. The introduction of functional pincer ligands that can store protons and/or electrons as expressed by metal–ligand cooperativity and ligand redox-activity strongly stimulated this development as a conceptual starting point for rational catalyst design. This review aims at providing a comprehensive picture of the utilization of functional pincer ligands in first-row transition metal hydrogenation and dehydrogenation catalysis and related synthetic concepts relying on these such as the hydrogen borrowing methodology. Particular emphasis is put on the implementation and relevance of cooperating and redox-active pincer ligands within the mechanistic scenarios.read more
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Journal ArticleDOI
Selective Hydrogenation over Supported Metal Catalysts: From Nanoparticles to Single Atoms
TL;DR: The key factors affecting the catalytic activity/selectivity, in particular, the geometric and electronic structure of the active sites, are discussed with the aim to extract fundamental principles for the development of efficient and selective catalysts in hydrogenation as well as other transformations.
Journal ArticleDOI
Strategies and mechanisms of metal-ligand cooperativity in first-row transition metal complex catalysts.
Matthew R. Elsby,R. Tom Baker +1 more
TL;DR: This review encapsulates advances made in metal-ligand cooperation by transition metal bifunctional catalysts over the last ten years, focusing exclusively on first-row transition metals, and highlighting significant contributions to mechanistic understanding.
Journal ArticleDOI
Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.
TL;DR: In this paper, a review of the development of homogeneous catalysts in emerging applications of sustainable energy is presented, focusing mainly on hydrogen storage and methanol production, with a focus on the use of pincer complexes.
Journal ArticleDOI
Iron- and Cobalt-Catalyzed Asymmetric Hydrofunctionalization of Alkenes and Alkynes
TL;DR: In this article, the authors proposed a chiral unsymmetric NNN-tridentate (UNT) ligand scaffolds for earth-abundant transition-metal catalysis.
Journal ArticleDOI
Is the H2 economy realizable in the foreseeable future? Part II: H2 storage, transportation, and distribution
Hassan Nazir,Navaneethan Muthuswamy,Navaneethan Muthuswamy,Cindrella Louis,Sujin P. Jose,Jyoti Prakash,Marthe Emelie Melandsø Buan,Cristina Flox,Sai Chavan,Xuan Shi,Pertti Kauranen,Tanja Kallio,Gilberto Maia,Kaido Tammeveski,Nikolaos Lymperopoulos,Elena Carcadea,Emre A. Veziroglu,Alfredo Iranzo,Arunachala Mada Kannan +18 more
TL;DR: A review series on the H2 economy is presented in this article to highlight the current status, major issues, and opportunities associated with H2 production, storage, transportation, distribution and usage in various energy sectors.
References
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