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Coordination geometries of selected transition metal ions (Co2+, Ni2+, Cu2+, Zn2+, Cd2+, and Hg2+) in metalloproteins.

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TLDR
The correlation between the geometries of small-molecule crystal structures and the metal-binding sites in metalloproteins was investigated and it follows that the octahedral arrangement is preferred by Co2+ and Ni2+, tetrahedral by Zn2+, square planar by Cu2+.
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This article is published in Journal of Inorganic Biochemistry.The article was published on 1998-09-01. It has received 369 citations till now. The article focuses on the topics: Coordination geometry.

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Citations
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Metalloproteins and metal sensing

TL;DR: Almost half of all enzymes must associate with a particular metal to function, and for metalloproteins to acquire the right metals, metal sensors must correctly distinguish between the inorganic elements.
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Protein-inorganic hybrid nanoflowers

TL;DR: A method is reported for creating hybrid organic-inorganic nanoflowers using copper (II) ions as the inorganic component and various proteins as the organic component to exhibit enhanced enzymatic activity and stability compared with the free enzyme.
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Natural antioxidants against lipid-protein oxidative deterioration in meat and meat products: A review.

TL;DR: The potential use of bioactive compounds in medicinal plants is reviewed as phytoremedy against lipid-protein oxidation and synergistic antimicrobial potentials of these natural antioxidants are revealed against oxidative deterioration in meat and meat products and, for enhancing their functional properties.
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Activation of estrogen receptor-alpha by the heavy metal cadmium.

TL;DR: The ability of cadmium to bind to and activate wild-type and various mutants of ER-alpha was examined, suggesting that the heavy metal interacts with the hormone-binding domain of the receptor.
References
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Book

Advanced Inorganic Chemistry

TL;DR: Cotton and Wilkinson's Advanced Inorganic Chemistry (AIC) as discussed by the authors is one of the most widely used inorganic chemistry books and has been used for more than a quarter century.
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Hard and soft acids and bases

TL;DR: In this paper, the rate data for the generalized nucleophilic displacement reaction were reviewed, and the authors presented a method to estimate the rate of the generalized displacement reaction in terms of the number of nucleophiles.
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Absolute hardness: companion parameter to absolute electronegativity

TL;DR: In this paper, a property called absolute hardness eta is defined for neutral and charged species, atomic and molecular, for both hard and soft acids and bases, by making use of the hypothesis that extra stability attends bonding of A to B when the ionization potentials of A and B in the molecule are the same.
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