Copper-catalyzed borylative transformations of non-polar carbon–carbon unsaturated compounds employing borylcopper as an active catalyst species
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In this paper, the fulltext file will be made open to the public on 15 April 2017 in accordance with publisher's 'Terms and Conditions for SelfArchiving', and the full-text file is made available under the CC-BY-NC-ND 4.0 license.About:
This article is published in Tetrahedron.The article was published on 2015-04-15 and is currently open access. It has received 222 citations till now. The article focuses on the topics: Copper & Borylation.read more
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Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse
TL;DR: Although known for over 90 years, only in the past two decades has the chemistry of diboron(4) compounds been extensively explored and these compounds now feature prominently in both metal-catalyzed and metal-free methodologies for the formation of B-C bonds and other processes.
Journal ArticleDOI
Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments
TL;DR: In this article, a boryl moiety across a carbon-carbon triple bond of alkynes is introduced, which is one of the most direct and potent methods for synthesizing alkenylboranes.
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Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis
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N-Heterocyclic Carbene Complexes of Copper, Nickel, and Cobalt
TL;DR: The emergence of N-heterocyclic carbenes as ligands across the Periodic Table had an impact on various aspects of the coordination, organometallic, and catalytic chemistry of the 3d metals, both from the fundamental viewpoint but also in applications.
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A Cu/Pd Cooperative Catalysis for Enantioselective Allylboration of Alkenes
TL;DR: A cooperative Cu/Pd-catalyzed asymmetric three-component reaction of styrenes, B2(pin)2, and allyl carbonates was reported and the utility of this protocol was demonstrated through the synthesis of an antipsychotic drug, (-)-preclamol.
References
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Palladium-catalyzed cross-coupling reactions of organoboron compounds
Norio Miyaura,Akira Suzuki +1 more
TL;DR: In this paper, a cross-coupling reaction is proposed for coupling 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6.
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C−H Activation for the Construction of C−B Bonds
TL;DR: Investigations revealed that the conversion of C-H bonds to C-B bonds was both thermodynamically and kinetically favorable and highlighted the accessible barriers for C- H bond cleavage and B-C bond formation during the borylation of alkanes and arenes.
Journal ArticleDOI
Palladium(0)-Catalyzed Cross-Coupling Reaction of Alkoxydiboron with Haloarenes: A Direct Procedure for Arylboronic Esters
TL;DR: In this article, a direct procedure for Arylboronic Esters was proposed for a cross-coupling reaction of Alkoxydiboron with Haloarenes.
Journal ArticleDOI
Rhodium-catalyzed asymmetric 1,4-addition and its related asymmetric reactions
Tamio Hayashi,Kaori Yamasaki +1 more
Journal ArticleDOI
Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations
TL;DR: The fundamental principles that govern the reactivity of intermediates containing metal-boron bonds are emphasized and how an understanding of the effects of the ligands on this reactivity led us to broaden the scope of main group reagents that react under mild conditions to generate synthetically useful organosilanes is described.
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