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Defect engineered mesoporous graphitic carbon nitride modified with AgPd nanoparticles for enhanced photocatalytic hydrogen evolution from formic acid

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TLDR
Wang et al. as mentioned in this paper developed a defect engineering strategy to construct N-deficient ordered mesoporous graphitic carbon nitride coupled with AgPd nanoparticles, and the as-prepared Ag0.1Pd0.9/N-ompg-C3N4 catalyst exhibits remarkable activity with the Turnover frequency (TOF) value of 1588.2h−1 and robust stability with only a slight decrease in activity after ten cycles.
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This article is published in Chemical Engineering Journal.The article was published on 2022-02-01. It has received 43 citations till now. The article focuses on the topics: Graphitic carbon nitride & Formic acid.

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Pd–WO heterostructures immobilized by MOFs-derived carbon cage for formic acid dehydrogenation

TL;DR: In this article , Pd-WOx nano-heterostructures (2.9 nm in diameter) anchored on ZIF-8 @ZIF-67 core-hell MOFs-derived nitrogen-doped porous carbon cage (NPCC) are fabricated for the first time through a phosphate mediation approach.
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Graphitic Carbon Nitride-based Nanostructures as Emergent Catalysts for Carbon Monoxide (CO) Oxidation

TL;DR: Graphitic carbon nitride nanostructures have attracted great attention in multidisciplinary energy and catalytic applications due to their outstanding physicochemical and catalyst/photocatalytic merits, besides ease of preparation from green, inexpensive, and... as mentioned in this paper .
Journal ArticleDOI

Tuning of graphitic carbon nitride (g-C3N4) for photocatalysis: A critical review

TL;DR: In this paper , the authors present the recent progress, perspectives, and persistent challenges in the development of g-C3N4-based photocatalytic materials, including metal and non-metal doping, co-doping, and heterojunction engineering.
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Efficient and Controlled H2 Release from Sodium Formate

TL;DR: Sodium formate (SF) has been used for a long time as a technological additive for H2 release from the dehydrogenation of formic acid as discussed by the authors , which is often synthesized from...
References
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Journal ArticleDOI

Graphitic Carbon Nitride (g-C3N4)-Based Photocatalysts for Artificial Photosynthesis and Environmental Remediation: Are We a Step Closer To Achieving Sustainability?

TL;DR: It is anticipated that this review can stimulate a new research doorway to facilitate the next generation of g-C3N4-based photocatalysts with ameliorated performances by harnessing the outstanding structural, electronic, and optical properties for the development of a sustainable future without environmental detriment.
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Polymeric Graphitic Carbon Nitride as a Heterogeneous Organocatalyst: From Photochemistry to Multipurpose Catalysis to Sustainable Chemistry

TL;DR: The "polymer chemistry" of g-C(3)N(4) is described, how band positions and bandgap can be varied by doping and copolymerization, and how the organic solid can be textured to make it an effective heterogenous catalyst.
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Alkali-Assisted Synthesis of Nitrogen Deficient Graphitic Carbon Nitride with Tunable Band Structures for Efficient Visible-Light-Driven Hydrogen Evolution.

TL;DR: A facile synthetic strategy for nitrogen-deficient graphitic carbon nitride (g-C3 Nx) is established, involving a simple alkali-assisted thermal polymerization of urea, melamine, or thiourea, with superior visible-light photocatalytic performance compared to pristine g-C2 N4.
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Homogeneous Catalysis for Sustainable Hydrogen Storage in Formic Acid and Alcohols.

TL;DR: In this paper, the authors describe the considerable progress that has been made in homogeneous catalysis for these critical reactions, namely, the hygienic reaction, and describe a review of the most relevant work in this area.
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Metal nanoparticles at mesoporous N-doped carbons and carbon nitrides: functional Mott-Schottky heterojunctions for catalysis.

TL;DR: This tutorial review highlights the latest development in the synthesis and applications of mesoporous N-doped carbon and carbon nitride supportedMetal nanoparticles, and concentrates on the catalytic effect of the charge transfer between the metal nanoparticles and semiconductive components.
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