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Journal ArticleDOI

Defect Engineering on Electrode Materials for Rechargeable Batteries.

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TLDR
Recent advances regarding defect engineering in electrode materials for rechargeable batteries are systematically summarized, with a special focus on the application of metal-ion batteries, lithium-sulfur batteries, and metal-air batteries.
Abstract
The reasonable design of electrode materials for rechargeable batteries plays an important role in promoting the development of renewable energy technology. With the in-depth understanding of the mechanisms underlying electrode reactions and the rapid development of advanced technology, the performance of batteries has significantly been optimized through the introduction of defect engineering on electrode materials. A large number of coordination unsaturated sites can be exposed by defect construction in electrode materials, which play a crucial role in electrochemical reactions. Herein, recent advances regarding defect engineering in electrode materials for rechargeable batteries are systematically summarized, with a special focus on the application of metal-ion batteries, lithium-sulfur batteries, and metal-air batteries. The defects can not only effectively promote ion diffusion and charge transfer but also provide more storage/adsorption/active sites for guest ions and intermediate species, thus improving the performance of batteries. Moreover, the existing challenges and future development prospects are forecast, and the electrode materials are further optimized through defect engineering to promote the development of the battery industry.

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Nitrogen-Doped Mesoporous Carbon Promoted Chemical Adsorption of Sulfur and Fabrication of High-Areal-Capacity Sulfur Cathode with Exceptional Cycling Stability for Lithium-Sulfur Batteries

TL;DR: In this article, a mesoporous nitrogen-doped carbon (MPNC)-sulfur nanocomposite is reported as a novel cathode for advanced Li-S batteries.
Journal ArticleDOI

Defect Engineering for Fuel‐Cell Electrocatalysts

TL;DR: The latest advances in defective electrocatalysts for ORR and HOR/SMOR in fuel cells are scientifically and systematically summarized and the structure-activity relationships between defect engineering and electrocatalyst ability are illustrated by coupling experimental results and theoretical calculations.
Journal ArticleDOI

Untangling Respective Effects of Heteroatom-doped Carbon Materials in Batteries, Supercapacitors and ORR to Design High-Performance Materials

TL;DR: In this article, a review comprehensively analyzes the relevant features of heteroatom-doped carbon composites used in batteries, supercapacitors, and the oxygen reduction reaction (ORR), and provides guidance for the design of more efficient materials.
Journal ArticleDOI

Defect chemistry in heterogeneous catalysis: recognition, understanding and utilization

TL;DR: In this paper, the authors proposed a method to find catalysts with high efficiency, low-cost and high stability for the research of heterogeneous catalysis, which plays an important role in modern industries.
Journal ArticleDOI

Dielectric Loss Mechanism in Electromagnetic Wave Absorbing Materials

TL;DR: In this article , comprehensive views toward dielectric loss mechanisms including interfacial polarization, dipolar polarization, conductive loss, and defect-induced polarization are provided, and in-depth losses and mechanisms regulation strategies instead of regular components compositing are summarized to provide inspiring thoughts toward simple and effective EM wave attenuation behavior modulation.
References
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Journal ArticleDOI

The Li-ion rechargeable battery: a perspective.

TL;DR: New strategies are needed for batteries that go beyond powering hand-held devices, such as using electrode hosts with two-electron redox centers; replacing the cathode hosts by materials that undergo displacement reactions; and developing a Li(+) solid electrolyte separator membrane that allows an organic and aqueous liquid electrolyte on the anode and cathode sides, respectively.
Journal ArticleDOI

Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction.

TL;DR: It is reported that vertically aligned nitrogen-containing carbon nanotubes (VA-NCNTs) can act as a metal-free electrode with a much better electrocatalytic activity, long-term operation stability, and tolerance to crossover effect than platinum for oxygen reduction in alkaline fuel cells.
Journal ArticleDOI

Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals

TL;DR: It is shown that disorder-engineered TiO2 nanocrystals exhibit substantial solar-driven photocatalytic activities, including the photo-oxidation of organic molecules in water and the production of hydrogen with the use of a sacrificial reagent.
Journal ArticleDOI

Structural defects in graphene

TL;DR: In this article, the present knowledge about point and line defects in graphene are reviewed and particular emphasis is put on the unique ability of graphene to reconstruct its lattice around intrinsic defects, leading to interesting effects and potential applications.
PatentDOI

Metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions

TL;DR: A mesoporous carbon foam co-doped with nitrogen and phosphorus that has a large surface area and good electrocatalytic properties for both ORR and OER and is tested as an air electrode for primary and rechargeable Zn-air batteries.
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