Journal ArticleDOI
Developing more sustainable processes for ammonia synthesis
Reads0
Chats0
TLDR
In this article, a transition metal-dinitrogen-bridged dimolybdenum complex bearing two PNP-type pincer ligands was used as a catalyst for the conversion of molecular dinitrogen into ammonia or ammonia equivalent, silylamine.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2013-09-01. It has received 316 citations till now. The article focuses on the topics: Ammonia production & Catalysis.read more
Citations
More filters
Journal ArticleDOI
Efficient Visible Light Nitrogen Fixation with BiOBr Nanosheets of Oxygen Vacancies on the Exposed {001} Facets
TL;DR: It is demonstrated that efficient fixation of N2 to NH3 can proceed under room temperature and atmospheric pressure in water using visible light illuminated BiOBr nanosheets of oxygen vacancies in the absence of any organic scavengers and precious-metal cocatalysts.
Journal ArticleDOI
Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage
TL;DR: This paper presents a meta-analyses of the chiral stationary phase replacement of Na6(CO3)(SO4)2, Na2SO4, and Na2CO3 of the H2O/O2 mixture and shows clear patterns in the response of these two types of molecules to each other in a stationary phase.
Journal ArticleDOI
A Review of Electrocatalytic Reduction of Dinitrogen to Ammonia under Ambient Conditions
TL;DR: In this paper, the authors summarized the recent progress on the electrochemical nitrogen reduction reaction (NRR) at ambient temperature and pressure from both theoretical and experimental aspects, aiming at extracting instructive perceptions for future NRR research activities.
Journal ArticleDOI
Defect Engineering Metal‐Free Polymeric Carbon Nitride Electrocatalyst for Effective Nitrogen Fixation under Ambient Conditions
Chade Lv,Chade Lv,Yumin Qian,Chunshuang Yan,Chunshuang Yan,Yu Ding,Yuanyue Liu,Gang Chen,Guihua Yu +8 more
TL;DR: A defect engineering strategy is reported to realize effective NRR performance on metal-free polymeric carbon nitride (PCN) catalyst and highlights the significance of defect engineering for improving electrocatalysts with weak N2 adsorption and activation ability.
Journal ArticleDOI
Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes.
Kristian E Dalle,Julien Warnan,Jane J. Leung,Bertrand Reuillard,Isabell S Karmel,Erwin Reisner +5 more
TL;DR: In this paper, a review of the literature on 3D metal-based molecular catalysts is presented, focusing on their immobilization on heterogeneous solid-state supports for the synthesis of renewable fuels from abundant water or greenhouse gas CO2.
References
More filters
Journal ArticleDOI
Preparation and characterization of two high oxidation state molybdenum dinitrogen complexes: [MoCp*Me3]2(.mu.-N2) and [MoCp*Me3](.mu.-N2)[WCp'Me3]
TL;DR: In this article, MeMgCl was alkylated by MeMmCl in tetrahydrofuran to give red microcrystalline MoCp{sup *}Me{sub 4} in {approximately}70% yield.
Journal ArticleDOI
The reactions of dinitrogen in its metal complexes
Joseph Chatt,Raymond L. Richards +1 more
Journal ArticleDOI
Catalytic fixation of molecular nitrogen by electrolytic and chemical reduction
Journal ArticleDOI
Synthesis of tungsten complexes that contain hexaisopropylterphenyl-substituted triamidoamine ligands, and reactions relevant to the reduction of dinitrogen to ammonia
TL;DR: In this paper, WCl can be synthesized readily by adding H3[HIPTN3N] to WCl4(DME) followed by LiN(SiMe3)2 and HIPT(3,5-(2,4,6-i-Pr3C6H2)2C 6H3) where HIPT
Journal ArticleDOI
Photocatalytic reduction of nitrogen over (Fe, Ru or Os)/TiO2 catalysts
TL;DR: In this article, the order of catalytic activity was found to be Ru > Fe > Os, while reverse order was found for the stability of the catalysts with respect to ammonia formation.