Journal ArticleDOI
Efficient Copper(I)-Catalyzed C–S Cross Coupling of Thiols with Aryl Halides in Water
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TLDR
In this paper, the C-S cross coupling of thiols with aryl halides in the presence of tetrabutylammonium bromide in water was investigated.About:
This article is published in European Journal of Organic Chemistry.The article was published on 2008-02-01. It has received 134 citations till now. The article focuses on the topics: Aryl.read more
Citations
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Transition-Metal-Catalyzed C−S, C−Se, and C−Te Bond Formation via Cross-Coupling and Atom-Economic Addition Reactions
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Copper catalysed Ullmann type chemistry: From mechanistic aspects to modern development
TL;DR: The history and development of coupling reactions between aryl halides and various classes of nucleophiles is discussed, focusing mostly on the different mechanisms proposed through the years.
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Catalytic Organic Reactions in Water toward Sustainable Society
TL;DR: This Review addresses advances over the past decade in catalytic reactions using water as a reaction medium by addressing the development of water-compatible catalysts and heterogeneous catalysts.
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CuO nanoparticles catalyzed C-N, C-O, and C-S cross-coupling reactions: scope and mechanism.
Suribabu Jammi,Sekarpandi Sakthivel,Laxmidhar Rout,Tathagata Mukherjee,Santu Mandal,Raja Mitra,Prasenjit Saha,Tharmalingam Punniyamurthy +7 more
TL;DR: CuO nanoparticles have been studied for C-N, C-O, and C-S bond formations via cross-coupling reactions of nitrogen, oxygen, and sulfur nucleophiles with aryl halides in the presence of a base such as KOH, Cs(2)CO(3), and K(2]CO( 3) at moderate temperature.
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The mechanism of the modified Ullmann reaction
TL;DR: A recent DFT study by Houk, Buchwald and co-workers shows that the modified Ullmann reaction between aryl iodide and amines or primary alcohols proceeds either via an SET or an IAT mechanism, suggesting a Cu(I)/Cu(III) type mechanism for the amidation (Goldberg) reaction.
References
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Aryl-aryl bond formation one century after the discovery of the Ullmann reaction.
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Modern Synthetic Methods for Copper‐Mediated C(aryl) ? O, C(aryl) ? N, and C(aryl) ? S Bond Formation
Steven V. Ley,Andrew Thomas +1 more
TL;DR: In this article, the authors highlight the recent developments in the copper-mediated (both stoichiometric and catalytic) reactions of aryl boronic acids as reaction partners in both O- and N-arylation.
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Rational Development of Practical Catalysts for Aromatic Carbon−Nitrogen Bond Formation
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Transition Metal Catalyzed Synthesis of Arylamines and Aryl Ethers from Aryl Halides and Triflates: Scope and Mechanism.
TL;DR: Oxidative addition and reductive elimination are the central steps in new palladium-catalyzed chemistry that forms C-N and C-O bonds in arylamines and ethers.
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