Journal ArticleDOI
Electrochemical Reaction Dynamics - A Review
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In this paper, the status of research on the dynamics of electrochemical reactions is reviewed, including the electrodissolution of metals, cathodic deposition, and electrocatalytic reactions.About:
This article is published in Chemical Engineering Science.The article was published on 1994-05-01. It has received 323 citations till now.read more
Citations
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Introduction to self-organization in chemical and electrochemical systems
TL;DR: Orlik et al. as discussed by the authors introduced the concept of nonlinearity of the system's dynamics and the presence of appropriately operating feedback loops in the kinetic mechanism to drive the system smoothly out from equilibrium, by simply varying the electrode potential or imposed current.
Journal ArticleDOI
On the stability of nonequilibrium steady-states for the electrode processes at a streaming mercury electrode
Marek Orlik,Rafal Jurczakowski +1 more
TL;DR: The streaming mercury electrode was found to be particularly useful for the study of nonlinear dynamical phenomena (oscillations and multistability) in the electroreduction of pseudohalogenide.
Journal ArticleDOI
Introduction to the dynamic self-organization of chemical systems
TL;DR: In this paper, the authors present a detailed discussion of the basic concepts of nonlinear dynamics in chemistry, such as multistability, spatiotemporal pattern formation, and deterministic chaos.
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In Situ CRM Study of the Self-Oscillating Cu-(II)-Lactate and Cu-(II)-Tartrate Systems
Sofia Leopold,J. C. Arrayet,Jean-Luc Bruneel,Merja Herranen,Jan Carlsson,Françoise Argoul,Laurent Servant +6 more
TL;DR: In this paper, an in situ spectroelectrochemical investigation of the spontaneous potential oscillations, galvanically induced in the Cu-(II)-lactate and -tartrate systems, has been performed using confocal Raman microspectroscopy (CRM).
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Dynamics of catalytic reactions and reactors
TL;DR: An overview of complex dynamic behavior in heterogeneous catalysis can be found in this article, where the issues discussed are the source of oscillatory behavior, classification of complex motions, transitions to chaotic solutions and spatiotemporal patterns in reactors of various geometries.
References
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Journal ArticleDOI
Determining Lyapunov exponents from a time series
TL;DR: In this article, the authors present the first algorithms that allow the estimation of non-negative Lyapunov exponents from an experimental time series, which provide a qualitative and quantitative characterization of dynamical behavior.
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Fractional Brownian Motions, Fractional Noises and Applications
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Measuring the Strangeness of Strange Attractors
TL;DR: In this paper, the correlation exponent v is introduced as a characteristic measure of strange attractors which allows one to distinguish between deterministic chaos and random noise, and algorithms for extracting v from the time series of a single variable are proposed.
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Ergodic theory of chaos and strange attractors
Jean-Pierre Eckmann,David Ruelle +1 more
TL;DR: A review of the main mathematical ideas and their concrete implementation in analyzing experiments can be found in this paper, where the main subjects are the theory of dimensions (number of excited degrees of freedom), entropy (production of information), and characteristic exponents (describing sensitivity to initial conditions).