Journal ArticleDOI
Elucidation of flexible metal-organic frameworks: Research progresses and recent developments
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TLDR
Flexibility is a unique property of metal-organic frameworks (MOFs) that differentiates them from other rigid inorganic porous materials such as zeolites and porous silica as discussed by the authors.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2019-06-15. It has received 130 citations till now.read more
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Fast parallel algorithms for short-range molecular dynamics
TL;DR: Comparing the results to the fastest reported vectorized Cray Y-MP and C90 algorithm shows that the current generation of parallel machines is competitive with conventional vector supercomputers even for small problems.
Journal ArticleDOI
A historical overview of the activation and porosity of metal–organic frameworks
Xuan Zhang,Zhijie Chen,Xinyao Liu,Xinyao Liu,Sylvia L. Hanna,Xingjie Wang,Reza Taheri-Ledari,Ali Maleki,Peng Li,Omar K. Farha +9 more
TL;DR: An overview of the historic evolution of porosity and activation of MOFs is provided, followed by a synopsis of the strategies to design and preserve permanent porosity in MOFs.
Journal ArticleDOI
Thermodynamics of Guest-Induced Structural Transitions in Hybrid Organic-Inorganic Frameworks
TL;DR: A taxonomy of guest-induced structural phase transitions and the corresponding isotherms is proposed and generic conditions for observing a double structural transition upon adsorption are derived, often resulting in a two-step isotherm.
Journal ArticleDOI
Chemistry of Soft Porous Crystals: Structural Dynamics and Gas Adsorption Properties.
TL;DR: The fundamental chemistry of SPCs is discussed by characterizing their common structural features and the resulting structural softness and transitions and focuses on the recently emerging properties based on metastable transitions and those arising from local dynamics.
Journal ArticleDOI
Luminescence response mode and chemical sensing mechanism for lanthanide-functionalized metal–organic framework hybrids
TL;DR: This comprehensive review systematically summarizes the luminescence response mode and chemical sensing mechanism for lanthanide-functionalized MOF hybrids (abbreviated as LnFMOFH).
References
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Fast parallel algorithms for short-range molecular dynamics
TL;DR: Comparing the results to the fastest reported vectorized Cray Y-MP and C90 algorithm shows that the current generation of parallel machines is competitive with conventional vector supercomputers even for small problems.
Journal ArticleDOI
GROMACS 4: Algorithms for highly efficient, load-balanced, and scalable molecular simulation
TL;DR: A new implementation of the molecular simulation toolkit GROMACS is presented which now both achieves extremely high performance on single processors from algorithmic optimizations and hand-coded routines and simultaneously scales very well on parallel machines.
Journal ArticleDOI
Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.
Journal ArticleDOI
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Kyo Sung Park,Zheng Ni,Adrien P. Côté,Jae Yong Choi,Rudan Huang,Fernando J. Uribe-Romo,Hee K. Chae,Michael O'Keeffe,Omar M. Yaghi +8 more
TL;DR: Study of the gas adsorption and thermal and chemical stability of two prototypical members, ZIF-8 and -11, demonstrated their permanent porosity, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvents.