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Enhancing Impact Resistance of Polymer Blends via Self-Assembled Nanoscale Interfacial Structures

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TLDR
In this paper, an environmentally sustainable ternary polymer blend with the mechanical properties comparable to high impact resistant conventional polymers under the guidance of the lattice self-consistent field model was designed and engineered.
Abstract
We have designed and engineered an environmentally sustainable ternary polymer blend with the mechanical properties comparable to high impact resistant conventional polymers under the guidance of the lattice self-consistent field model. In this blend system, poly(methyl methacrylate) (PMMA) was used as the compatibilizer for the poly(lactic acid) (PLA)/poly(butylene adipate-co-butylene terephthalate) (PBAT) blend. We characterized the compatibility of those components and found PMMA was miscible with PLA and partially compatible with PBAT, which allowed it to self-assemble to a nanoscale interfacial layer on the PLA/PBAT interface. This PMMA layer can significantly decrease the interfacial energy and strongly entangle with either PLA or PBAT, resulting in the strengthening of the interface and dramatically enhancement of the impact resistance of the ternary blend. The optimal mechanical performance was achieved when the total PMMA concentration was less than 10 wt %. Higher PMMA content embrittled the ble...

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Journal ArticleDOI

Ultrathin flexible poly(vinylidene fluoride)/MXene/silver nanowire film with outstanding specific EMI shielding and high heat dissipation

TL;DR: In this article, ultrathin flexible polyvinylidene fluoride (PVDF) composite films with MXenes and silver nanowires (AgNWs) were prepared via solution casting method.
Journal ArticleDOI

Selective electromagnetic interference shielding performance and superior mechanical strength of conductive polymer composites with oriented segregated conductive networks

TL;DR: In this article, an oriented segregated structure was achieved in carbon nanotube (CNT)/ultra high molecular weight polyethylene (UHMWPE) composites via solid phase stretching and the orientation of segregated network was controlled by adopting different draw ratios.
Journal ArticleDOI

An Effective Design Strategy for the Sandwich Structure of PVDF/GNP-Ni-CNT Composites with Remarkable Electromagnetic Interference Shielding Effectiveness.

TL;DR: A novel 3-layered sandwich structure of poly(vinylidene fluoride) (PVDF) based nanocomposites, consisting of graphene nanoplatelets (GNP), nickel (Ni) and carbon nanotubes (CNT) exhibited excellent EMI shielding ability, presenting tremendous opportunities to design and manufacture advanced E MI shielding materials and equipment.
Journal ArticleDOI

Nacre-like composite films with high thermal conductivity, flexibility, and solvent stability for thermal management applications

TL;DR: In this paper, the polydopamine (PDA)-coated boron nitride nanoplatelets (BNNS@PDA)/polyvinyl alcohol (PVA) composite films with a unique nacre-like structure via a facile vacuum-assisted self-assembly process.
Journal ArticleDOI

Promising PVC/MXene based flexible thin film nanocomposites with excellent dielectric, thermal and mechanical properties

TL;DR: In this paper, the authors focused on the synthesis and characterization of strong and flexible PVC/MXene nanocomposites, possessing high dielectric constant and minimum energy loss, for their use in energy storage electronic applications.
References
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Journal ArticleDOI

Production, use, and fate of all plastics ever made

TL;DR: By identifying and synthesizing dispersed data on production, use, and end-of-life management of polymer resins, synthetic fibers, and additives, this work presents the first global analysis of all mass-produced plastics ever manufactured.
Journal ArticleDOI

Biodegradable Polymers for the Environment

TL;DR: The need to create alternative biodegradable water-soluble polymers for down-the-drain products such as detergents and cosmetics has taken on increasing importance, forcing industry to compete head-to-head on a cost-performance basis with existing familiar products.
Journal ArticleDOI

Phase structure and adhesion in polymer blends: a criterion for rubber toughening

Souheng Wu
- 01 Nov 1985 - 
TL;DR: In this paper, the effects of rubber particle size and rubber-matrix adhesion on notched impact toughness of nylon-rubber blends are analyzed. And the general condition for toughening is that the interparticle distance must be smaller than the critical value.
Journal ArticleDOI

Large-scale production, properties and commercial applications of polylactic acid polymers

TL;DR: In this paper, the authors discuss the various technologies being used to produce polylactic acids and how monomer stereochemistry can be controlled to impart targeted utility in the final polymers.
Journal ArticleDOI

Statistical Theory of the Adsorption of Interacting Chain Molecules. 1. Partition Function, Segment Density Distribution, and Adsorption Isotherms

TL;DR: In this article, a general theory for polymer adsorption using a quasi-crystalline lattice model is presented, where the Bragg-Williams approximation of random mixing within each layer parallel to the surface is adopted.
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