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Fast pyrolysis processes for biomass

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TLDR
Fast pyrolysis for production of liquids has developed considerably since the first experiments in the late 1970s as mentioned in this paper, leading to significant advances in process development and a wide range of reactor configurations that have been developed to meet the stringent requirements for high yields of useful liquids, for use as a fuel in boilers, engines and turbines and as a source of chemical commodities.
Abstract
Fast pyrolysis for production of liquids has developed considerably since the first experiments in the late 1970s. Many reactors and processes have been investigated and developed to the point where fast pyrolysis is now an accepted feasible and viable route to renewable liquid fuels, chemicals and derived products. It is also now clear that liquid products offer significant advantages in storage and transport over gas and heat. These advantages have caused greater attention to be paid to fast pyrolysis, leading to significant advances in process development. The technology of fast pyrolysis for liquids is noteworthy for the wide range of reactor configurations that have been developed to meet the stringent requirements for high yields of useful liquids, for use as a fuel in boilers, engines and turbines and as a source of chemical commodities. This review summarizes the key features of fast pyrolysis and the resultant liquid product and describes the major reaction systems and processes that have been developed over the last 20 years.

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Citations
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Journal ArticleDOI

Effects of particle size, pretreatment, and catalysis on microwave pyrolysis of corn stover

TL;DR: In this article, the effects of particle size, pretreatment (acid pretreatment and steam explosion), and catalysis of aluminum oxide (Al2O3) on heating efficiency, product distribution, and gaseous product composition of corn stover pyrolysis using microwave heating were investigated.
Journal ArticleDOI

Bifunctional Ni-ZSM-5 Catalysts for the Pyrolysis and Hydropyrolysis of Biomass

TL;DR: In this article, the authors explore pyrolysis options, namely, high pressure, H2, and metal-loaded ZSM-5 catalysts, to improve the limited deoxygenation capacity and reduce the excessive production of solids.
Journal ArticleDOI

Design, Construction, and Operation of a Transported Fluid Bed Process Development Unit for Biomass Fast Pyrolysis: Effect of Pyrolysis Temperature

TL;DR: In this article, the authors investigated biomass fast pyrolysis process in a novel once-through transported fluid bed process development unit, where the main part of the unit is a specially designed mixing zone where the solid heat carrier mixes with the biomass feed.
Journal ArticleDOI

Effect of Zn/Al ratio of Ni/ZnO-Al2O3 catalysts on the catalytic deoxygenation of oleic acid into alkane

TL;DR: In this article, the effects of the Zn/Al ratio on the physico-chemical properties of the supports and the deoxygenation activity of the final catalyst were investigated in detail.
Journal ArticleDOI

Two-stage catalytic fast hydropyrolysis of biomass for the production of drop-in biofuel

TL;DR: In this article, the introduction of high pressure hydrogen into the pyrolysis reactor was studied, in a process known as catalytic fast hydropy rolysis (CFHP).
References
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Journal ArticleDOI

Molecular characterization of the pyrolysis of biomass

Robert J. Evans, +1 more
- 01 Mar 1987 - 
TL;DR: Application de la spectrometrie de masse a faisceau a l'etude des mecanismes moleculaires de la pyrolyse du bois and de ses principaux constituants (cellulose, lignine et hemicellulose).
Journal ArticleDOI

Catalysis in thermal biomass conversion

TL;DR: In this paper, the authors describe the technologies of gasification, pyrolysis and liquefaction of biomass with particular reference to the use of catalysts, and use catalytic processes in upgrading primary products from thermochemical conversion to higher quality and value fuels and chemicals.
BookDOI

Fundamentals of thermochemical biomass conversion

TL;DR: In this paper, Wood and biomass ultrastructure, Cellulose, hemicellulose and extractives, Lignin, pretreatment of biomass for thermochemical biomass conversion, a kinetic isotope effect in the thermal dehydration of cellobiose; Gasification and liquefaction of forest products in supercritical water; Thermochemical fractionation and liquifaction of wood; The pyrolysis and gasification of wood in molten hydroxide eutectics.
BookDOI

Developments in thermochemical biomass conversion

TL;DR: In this paper, the authors present an analysis and characterisation of pyrolysis liquid and demonstrate its performance in the laboratory and in the real world using pilot and demonstrator demonstrations.
Journal ArticleDOI

The pyrolysis of scrap automotive tyres

TL;DR: In this article, pyrolysis temperatures up to 720 °C and at heating rates between 5 and 80 °C min−1 were used to determine the composition and properties of the derived gases and oils.
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