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Fast pyrolysis processes for biomass

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TLDR
Fast pyrolysis for production of liquids has developed considerably since the first experiments in the late 1970s as mentioned in this paper, leading to significant advances in process development and a wide range of reactor configurations that have been developed to meet the stringent requirements for high yields of useful liquids, for use as a fuel in boilers, engines and turbines and as a source of chemical commodities.
Abstract
Fast pyrolysis for production of liquids has developed considerably since the first experiments in the late 1970s. Many reactors and processes have been investigated and developed to the point where fast pyrolysis is now an accepted feasible and viable route to renewable liquid fuels, chemicals and derived products. It is also now clear that liquid products offer significant advantages in storage and transport over gas and heat. These advantages have caused greater attention to be paid to fast pyrolysis, leading to significant advances in process development. The technology of fast pyrolysis for liquids is noteworthy for the wide range of reactor configurations that have been developed to meet the stringent requirements for high yields of useful liquids, for use as a fuel in boilers, engines and turbines and as a source of chemical commodities. This review summarizes the key features of fast pyrolysis and the resultant liquid product and describes the major reaction systems and processes that have been developed over the last 20 years.

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Citations
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Journal ArticleDOI

Development and application of a continuous fast microwave pyrolysis system for sewage sludge utilization.

TL;DR: A continuous fast microwave-assisted pyrolysis system was designed, fabricated, and tested with sewage sludge, and the absence of carrier gas in the process may be responsible for the high HHV of gas products.
Journal ArticleDOI

Modeling fast biomass pyrolysis in a gas/solid vortex reactor

TL;DR: In this paper, pyrolysis of lignocellulosic biomass in a gas/solid vortex reactor (GSVR) is modeled to assess the potential of this centrifugal fluidization reactor technology and to explore its process intensification abilities.
Journal ArticleDOI

Co-pyrolysis of coal and raw/torrefied biomass: A review on chemistry, kinetics and implementation

TL;DR: In this paper, the authors evaluate the performance of co-pyrolysis of torrefied biomass and coal and conclude on the preferred reactor design for this process, different reactors were evaluated based on heat transfer mode, operation and product formation.
Journal ArticleDOI

Selective fast pyrolysis of biomass impregnated with ZnCl2: Furfural production together with acetic acid and activated carbon as by-products

TL;DR: In this article, a lab-scale fast pyrolysis set was designed and used for the quantitative production of the three chemicals, including furfural (FF), acetic acid (AA), and activated carbons (ACs).
Journal ArticleDOI

Catalytic conversion of carboxylic acids in bio-oil for liquid hydrocarbons production

TL;DR: In this article, the performance of acetic acid and propanoic acid in the production of liquid hydrocarbons during a catalytic conversion process was investigated in a micro-fixed bed reactor.
References
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Journal ArticleDOI

Molecular characterization of the pyrolysis of biomass

Robert J. Evans, +1 more
- 01 Mar 1987 - 
TL;DR: Application de la spectrometrie de masse a faisceau a l'etude des mecanismes moleculaires de la pyrolyse du bois and de ses principaux constituants (cellulose, lignine et hemicellulose).
Journal ArticleDOI

Catalysis in thermal biomass conversion

TL;DR: In this paper, the authors describe the technologies of gasification, pyrolysis and liquefaction of biomass with particular reference to the use of catalysts, and use catalytic processes in upgrading primary products from thermochemical conversion to higher quality and value fuels and chemicals.
BookDOI

Fundamentals of thermochemical biomass conversion

TL;DR: In this paper, Wood and biomass ultrastructure, Cellulose, hemicellulose and extractives, Lignin, pretreatment of biomass for thermochemical biomass conversion, a kinetic isotope effect in the thermal dehydration of cellobiose; Gasification and liquefaction of forest products in supercritical water; Thermochemical fractionation and liquifaction of wood; The pyrolysis and gasification of wood in molten hydroxide eutectics.
BookDOI

Developments in thermochemical biomass conversion

TL;DR: In this paper, the authors present an analysis and characterisation of pyrolysis liquid and demonstrate its performance in the laboratory and in the real world using pilot and demonstrator demonstrations.
Journal ArticleDOI

The pyrolysis of scrap automotive tyres

TL;DR: In this article, pyrolysis temperatures up to 720 °C and at heating rates between 5 and 80 °C min−1 were used to determine the composition and properties of the derived gases and oils.
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