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Fast pyrolysis processes for biomass

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TLDR
Fast pyrolysis for production of liquids has developed considerably since the first experiments in the late 1970s as mentioned in this paper, leading to significant advances in process development and a wide range of reactor configurations that have been developed to meet the stringent requirements for high yields of useful liquids, for use as a fuel in boilers, engines and turbines and as a source of chemical commodities.
Abstract
Fast pyrolysis for production of liquids has developed considerably since the first experiments in the late 1970s. Many reactors and processes have been investigated and developed to the point where fast pyrolysis is now an accepted feasible and viable route to renewable liquid fuels, chemicals and derived products. It is also now clear that liquid products offer significant advantages in storage and transport over gas and heat. These advantages have caused greater attention to be paid to fast pyrolysis, leading to significant advances in process development. The technology of fast pyrolysis for liquids is noteworthy for the wide range of reactor configurations that have been developed to meet the stringent requirements for high yields of useful liquids, for use as a fuel in boilers, engines and turbines and as a source of chemical commodities. This review summarizes the key features of fast pyrolysis and the resultant liquid product and describes the major reaction systems and processes that have been developed over the last 20 years.

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Citations
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Journal ArticleDOI

Catalytic conversion of biomass pyrolysis products by mesoporous materials: Effect of steam stability and acidity of Al-MCM-41 catalysts

TL;DR: In this paper, two mesoporous aluminosilicate MCM-41 materials (Si/Al = 30 or 50) were tested as catalysts for the in situ upgrading of biomass pyrolysis vapours in comparison to a siliceous MCM41 sample and to non-catalytic biomass pyrotechnics.
Journal ArticleDOI

Physiochemical properties of bio-oil produced at various temperatures from pine wood using an auger reactor.

TL;DR: The study found that the concentration of phenol and its derivatives increased with the increase in pyrolysis temperature whereas the concentrationof guaiacol and their derivatives decreased as the temperature increased, although the pH value of the bio-oil decreased with the increases in temperature.
Journal ArticleDOI

Processing thermogravimetric analysis data for isoconversional kinetic analysis of lignocellulosic biomass pyrolysis: Case study of corn stalk

TL;DR: In this paper, a detailed isoconversional kinetic analysis of TGA data obtained from the pyrolysis of corn stalks at five heating rates was presented, and the results have shown that the effective activation energies of corn stalk pyrotechnics vary from 148 to 473 kJ mol−1 when the conversion ranges from 0.05 to 0.85.
Journal ArticleDOI

An outlook of Malaysian energy, oil palm industry and its utilization of wastes as useful resources

TL;DR: In this paper, a detailed representation of oil palm planted and produced together with its yield from the year 1976 onwards is given in Malaysia, where palm oil and related products represent the second largest export of Malaysia.
References
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Journal ArticleDOI

Molecular characterization of the pyrolysis of biomass

Robert J. Evans, +1 more
- 01 Mar 1987 - 
TL;DR: Application de la spectrometrie de masse a faisceau a l'etude des mecanismes moleculaires de la pyrolyse du bois and de ses principaux constituants (cellulose, lignine et hemicellulose).
Journal ArticleDOI

Catalysis in thermal biomass conversion

TL;DR: In this paper, the authors describe the technologies of gasification, pyrolysis and liquefaction of biomass with particular reference to the use of catalysts, and use catalytic processes in upgrading primary products from thermochemical conversion to higher quality and value fuels and chemicals.
BookDOI

Fundamentals of thermochemical biomass conversion

TL;DR: In this paper, Wood and biomass ultrastructure, Cellulose, hemicellulose and extractives, Lignin, pretreatment of biomass for thermochemical biomass conversion, a kinetic isotope effect in the thermal dehydration of cellobiose; Gasification and liquefaction of forest products in supercritical water; Thermochemical fractionation and liquifaction of wood; The pyrolysis and gasification of wood in molten hydroxide eutectics.
BookDOI

Developments in thermochemical biomass conversion

TL;DR: In this paper, the authors present an analysis and characterisation of pyrolysis liquid and demonstrate its performance in the laboratory and in the real world using pilot and demonstrator demonstrations.
Journal ArticleDOI

The pyrolysis of scrap automotive tyres

TL;DR: In this article, pyrolysis temperatures up to 720 °C and at heating rates between 5 and 80 °C min−1 were used to determine the composition and properties of the derived gases and oils.
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