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Fast pyrolysis processes for biomass

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TLDR
Fast pyrolysis for production of liquids has developed considerably since the first experiments in the late 1970s as mentioned in this paper, leading to significant advances in process development and a wide range of reactor configurations that have been developed to meet the stringent requirements for high yields of useful liquids, for use as a fuel in boilers, engines and turbines and as a source of chemical commodities.
Abstract
Fast pyrolysis for production of liquids has developed considerably since the first experiments in the late 1970s. Many reactors and processes have been investigated and developed to the point where fast pyrolysis is now an accepted feasible and viable route to renewable liquid fuels, chemicals and derived products. It is also now clear that liquid products offer significant advantages in storage and transport over gas and heat. These advantages have caused greater attention to be paid to fast pyrolysis, leading to significant advances in process development. The technology of fast pyrolysis for liquids is noteworthy for the wide range of reactor configurations that have been developed to meet the stringent requirements for high yields of useful liquids, for use as a fuel in boilers, engines and turbines and as a source of chemical commodities. This review summarizes the key features of fast pyrolysis and the resultant liquid product and describes the major reaction systems and processes that have been developed over the last 20 years.

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Citations
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Journal ArticleDOI

Fast pyrolysis of microalgae in a falling solids reactor: Effects of process variables and zeolite catalysts

TL;DR: In this paper, non-catalytic and catalytic pyrolysis of microalgae were carried out to generate an organic liquid fuel precursor, and the impacts of several process variables on the fast pyroglysis in a falling solids reactor are reported, including temperature, particle size, flow rate, and atmosphere (N 2, H 2 O and CO 2 ).
Journal ArticleDOI

Non-isothermal pyrolysis of pectin: A thermochemical and kinetic approach

TL;DR: In this article, the thermal degradation of pectin was investigated by simultaneous TGA-DSC/FTIR analysis and Hi-Res/modulated-TGA technique under nitrogen atmosphere.
Journal ArticleDOI

A review on pyrolysis of protein-rich biomass: Nitrogen transformation

TL;DR: The present review comprehensively summarized the effects of biomass compositions and pyrolysis parameters on the contents of N and the N-containing chemical components in bio-oil and identified the research gaps.
Journal ArticleDOI

Bio-oil production from hydrothermal liquefaction of high-protein high-ash microalgae including wild Cyanobacteria sp. and cultivated Bacillariophyta sp.

TL;DR: In this paper, the authors examined the decomposition behavior of two kinds of high-protein high-ash microalgae, including wild Cyanobacteria sp. and cultivated Bacillariophyta sp., via hydrothermal liquefaction (HTL).
Journal ArticleDOI

Bio-oil hydrodeoxygenation: Adsorption of phenolic compounds on sulfided (Co)Mo catalysts

TL;DR: In this article, the authors reported the interaction of aromatic compounds (as phenol, ethylphenols, and guaiacol) representative of oxygenated functions of pyrolysis bio-oils, with sulfided (Co)Mo/Al 2 O 3 catalyst in order to determine the origin of catalyst deactivation in hydrodeoxygenation (HDO) reaction.
References
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Journal ArticleDOI

Molecular characterization of the pyrolysis of biomass

Robert J. Evans, +1 more
- 01 Mar 1987 - 
TL;DR: Application de la spectrometrie de masse a faisceau a l'etude des mecanismes moleculaires de la pyrolyse du bois and de ses principaux constituants (cellulose, lignine et hemicellulose).
Journal ArticleDOI

Catalysis in thermal biomass conversion

TL;DR: In this paper, the authors describe the technologies of gasification, pyrolysis and liquefaction of biomass with particular reference to the use of catalysts, and use catalytic processes in upgrading primary products from thermochemical conversion to higher quality and value fuels and chemicals.
BookDOI

Fundamentals of thermochemical biomass conversion

TL;DR: In this paper, Wood and biomass ultrastructure, Cellulose, hemicellulose and extractives, Lignin, pretreatment of biomass for thermochemical biomass conversion, a kinetic isotope effect in the thermal dehydration of cellobiose; Gasification and liquefaction of forest products in supercritical water; Thermochemical fractionation and liquifaction of wood; The pyrolysis and gasification of wood in molten hydroxide eutectics.
BookDOI

Developments in thermochemical biomass conversion

TL;DR: In this paper, the authors present an analysis and characterisation of pyrolysis liquid and demonstrate its performance in the laboratory and in the real world using pilot and demonstrator demonstrations.
Journal ArticleDOI

The pyrolysis of scrap automotive tyres

TL;DR: In this article, pyrolysis temperatures up to 720 °C and at heating rates between 5 and 80 °C min−1 were used to determine the composition and properties of the derived gases and oils.
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