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Journal ArticleDOI

Graphene oxide stabilized polyethylene glycol for heat storage

TLDR
Because of the high heat storage capacity and the moderate phase change temperature, the PEG-GO composite is a promising heat energy storage candidate at mild temperature.
Abstract
Graphene oxide (GO) sheets were introduced to stabilize the melted polyethylene glycol (PEG) during the solid–liquid phase change process, which can be used as a smart heat storage system. The structural properties and phase change behaviors of the PEG–GO composites were comprehensively investigated as a function of the PEG content by means of various characterization techniques. The highest stabilized PEG content is 90 wt% in the composites, resulting in a heat storage capacity of 156.9 J g−1, 93.9% of the phase change enthalpy of pure PEG. Notably, GO has much stronger impact on lowering of the phase change temperature of PEG compared with some other porous carbon materials (activated carbon and ordered mesoporous carbon) due to the unique thin layer structure of GO. Because of the high heat storage capacity and the moderate phase change temperature, the PEG–GO composite is a promising heat energy storage candidate at mild temperature.

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Journal ArticleDOI

Nanoconfined phase change materials for thermal energy applications

TL;DR: In this article, a review summarizes the recent advancement and critical issues of nanoconfinement technologies of phase change materials from the point of view of material design, and the potential applications of nan-fined PCMs in diverse fields, including energy conversion and storage, thermal rectification and temperature controlled drug delivery systems, are presented in detail.
Journal ArticleDOI

Cellulose/graphene aerogel supported phase change composites with high thermal conductivity and good shape stability for thermal energy storage

TL;DR: In this article, a phase change composites is prepared by vacuum assisted impregnating of polyethylene glycol (PEG) into the cellulose/GNP aerogels, which exhibit high thermal conductivity, good shape stability and high latent heat of fusion.
Journal ArticleDOI

Role of oxygen functional groups in reduced graphene oxide for lubrication

TL;DR: Antiwear properties of hydroxyl-terminated rGO were significantly enhanced compared to epoxy-hydroxyl functionalized rGO due to the integrity of graphene sheet clusters, and the friction coefficient was unaffected when hydroxy-terminate rGO was coupled with PEG.
Journal ArticleDOI

Hybrid graphene aerogels/phase change material composites: Thermal conductivity, shape-stabilization and light-to-thermal energy storage

TL;DR: Hybrid graphene aerogels (HGA) consisting of graphene oxide (GO) and graphene nanoplatelets (GNP) were prepared and introduced into polyethylene glycol (PEG) via vacuum impregnation, aiming at obtaining composite phase change materials (PCMs) with high thermal conductivity, outstanding shape-stabilization, high energy storage density, commendable thermal repeatability and the ability to light-to-heat energy storage.
Journal ArticleDOI

Honeycomb-like structured biological porous carbon encapsulating PEG: A shape-stable phase change material with enhanced thermal conductivity for thermal energy storage

TL;DR: In this article, a composite phase change materials (c-PCMs) composed of polyethylene glycol (PEG) and biological porous carbon (BPC) is investigated.
References
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Journal ArticleDOI

The chemistry of graphene oxide

TL;DR: This review will be of value to synthetic chemists interested in this emerging field of materials science, as well as those investigating applications of graphene who would find a more thorough treatment of the chemistry of graphene oxide useful in understanding the scope and limitations of current approaches which utilize this material.
Journal ArticleDOI

Layer-by-Layer Assembly of Ultrathin Composite Films from Micron-Sized Graphite Oxide Sheets and Polycations

TL;DR: In this article, unilamellar colloids of graphite oxide (GO) were prepared from natural graphite and were grown as monolayer and multilayer thin films on cationic surfaces by electrostatic self-assembly.
Journal ArticleDOI

Structure of Graphite Oxide Revisited

TL;DR: In this paper, the authors used 13C and 1H NMR spectra of graphite oxide derivatives to confirm the assignment of the 70 ppm line to C−OH groups and allow them to propose a new structural model for graphite oxides.
Journal ArticleDOI

Thin-film particles of graphite oxide 1:: High-yield synthesis and flexibility of the particles

TL;DR: In this paper, a modified Hummers' method was used to synthesize thin-film graphite oxide particles with high yield by combining a very long oxidation period with a high purity purification process.
Journal ArticleDOI

A review on phase-change materials: Mathematical modeling and simulations

TL;DR: In this article, a review of phase-change materials (PCMs) behavior prediction is presented, based on the first law and on the second law of thermodynamics, with selected results for several configurations, from numerous authors.
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