Journal ArticleDOI
Green acetalization of glycerol and carbonyl catalyzed by FeCl3·6H2O
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TLDR
In this article, a new and mild method of glycerol acetalization reaction with various carbonyl compounds catalyzed by the cheap and simple iron catalyst FeCl3·6H2O has been developed.About:
This article is published in Molecular Catalysis.The article was published on 2017-09-01. It has received 36 citations till now. The article focuses on the topics: Glycerol.read more
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Journal ArticleDOI
Iron(III) Complexes with Cross-Bridged Cyclams: Synthesis and Use in Alcohol and Water Oxidation Catalysis
Alfonso Annunziata,Roberto Esposito,Giordano Gatto,Maria Elena Cucciolito,Angela Tuzi,Alceo Macchioni,Francesco Ruffo +6 more
Journal ArticleDOI
Iron(III) Complexes for Highly Efficient and Sustainable Ketalization of Glycerol: A Combined Experimental and Theoretical Study.
Roberto Esposito,Umberto Raucci,Maria Elena Cucciolito,Rossella Di Guida,Carmen Scamardella,Nadia Rega,Francesco Ruffo +6 more
TL;DR: A very promising and eco-friendly transformation of glycerol in nontoxic solvents and chemicals (i.e., solketal, ketals), proposing three new families of Fe(III) compounds capable of catalysing Glycerol acetalization with unpublished turn over frequencies (TOFs), and adhering most of the principles of green chemistry.
Journal ArticleDOI
Acetalization of glycerol with acetone over Co[II](Co[III]xAl2−x)O4 derived from layered double hydroxide
TL;DR: In this paper, a series of solid acid Co[II]-Co[III]xAl2−x)O4 catalysts were used in the acetalization of glycerol with acetone.
Journal ArticleDOI
On the reasons for deactivation of titanate nanotubes with metals catalysts in the acetalization of glycerol with acetone
Igor S. Gomes,Davi C. Carvalho,Alcineia C. Oliveira,Enrique Rodríguez-Castellón,Samuel Tehuacanero-Cuapa,Paulo Freire,Josué Mendes Filho,Gilberto Dantas Saraiva,Francisco F. de Sousa,Francisco F. de Sousa,Rossano Lang +10 more
TL;DR: In this article, the performance of Co and Ni-containing titanate nanotubes (CTNT) catalysts was investigated for glycerol acetalization with acetone.
Journal ArticleDOI
Solvent-free transesterification of methyl levulinate and esterification of levulinic acid catalyzed by a homogeneous iron(III) dimer complex
Massimo Melchiorre,Raffaele Amendola,Vincenzo Benessere,Maria Elena Cucciolito,Francesco Ruffo,Roberto Esposito +5 more
TL;DR: In this article, a variety of levulinates (R= n-butyl, n-hexyl and n-octyl) were derived from the solvent-free transesterification of methyl levulinate (ML) and esterification of Levulinic acid (LA), catalyzed by a dimeric complex of iron(III).
References
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Journal ArticleDOI
Technical aspects of biodiesel production by transesterification—a review
TL;DR: In this paper, various methods of preparation of biodiesel with different combination of oil and catalysts have been described and technical tools and processes for monitoring the transesterification reactions like TLC, GC, HPLC, GPC, 1H NMR and NIR have also been summarized.
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Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals
TL;DR: This paper provides a comprehensive review and critical analysis on the different reaction pathways for catalytic conversion of glycerol into commodity chemicals, including selective oxidation, selective hydrogenolysis, selective dehydration, pyrolysis and gasification, steam reforming, thermal reduction into syngas, selective transesterification, selective etherification, oligomerization and polymerization, and conversion of Glycerol carbonate.
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From glycerol to value-added products.
TL;DR: This Minireview shows how glycerol will be a central raw material in future chemical industries.
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Improved utilisation of renewable resources: New important derivatives of glycerol
TL;DR: A broad overview on the chemistry of glycerol starting from the classic esters and oligomers to new products like glycerols carbonate, telomers, branched alkyl ethers, propanediols and epoxides is given in this article.
Journal ArticleDOI
Low-pressure hydrogenolysis of glycerol to propylene glycol
TL;DR: In this paper, a new reaction pathway for converting glycerol to propylene glycol via an intermediate was validated by isolating the acetol intermediate, and the results showed that the yield of glycerols increased with decreasing water content.