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Open AccessJournal ArticleDOI

Highly sensitive and selective liquid crystal optical sensor for detection of ammonia.

TLDR
A highly sensitive and selective optical sensor for detection of ammonia (NH3) based on liquid crystals (LCs) that can be a sensitive detection platform for other molecule monitors such as proteins, DNAs and other heavy metal ions by modifying sensing molecules.
Abstract
Ammonia detection technologies are very important in environment monitoring. However, most existing technologies are complex and expensive, which limit the useful range of real-time application. Here, we propose a highly sensitive and selective optical sensor for detection of ammonia (NH3) based on liquid crystals (LCs). This optical sensor is realized through the competitive binding between ammonia and liquid crystals on chitosan-Cu2+ that decorated on glass substrate. We achieve a broad detection range of ammonia from 50 ppm to 1250 ppm, with a low detection limit of 16.6 ppm. This sensor is low-cost, simple, fast, and highly sensitive and selective for detection of ammonia. The proposal LC sensing method can be a sensitive detection platform for other molecule monitors such as proteins, DNAs and other heavy metal ions by modifying sensing molecules.

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Citations
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Journal ArticleDOI

Thermotropic Liquid Crystal-Assisted Chemical and Biological Sensors

TL;DR: This review article examines recent progress in the application of liquid crystal-assisted advanced functional materials for sensing biological and chemical analytes and suggests possible means of bridging scientific findings to viable and attractive LC sensor platforms.
Journal ArticleDOI

Seeing the Unseen: The Role of Liquid Crystals in Gas-Sensing Technologies.

TL;DR: Sensing platforms utilizing thermotropic uniaxial systems—nematic and smectic—that exploit not only interfacial phenomena, but also changes in the LC bulk, are demonstrated and special focus is given to the different interaction mechanisms and tuned selectivity toward gas and VOC analytes.
Journal ArticleDOI

Liquid crystal/polymer fiber mats as sensitive chemical sensors

TL;DR: In this article, the optical response of liquid crystal (LC)/polymer composite fiber mats to toluene and acetone vapors was analyzed and shown that the chemicals can pass through the polymer sheath of the fibers and be absorbed by the core.
Journal ArticleDOI

Materials and methods of biosensor interfaces with stability

TL;DR: In this article, the authors summarized the latest methods and materials used to construct stable biosensor interfaces, and pointed some future perspectives and challenges of them, and found that nanomaterials, polymers as well as their composites such as chitosan, cellulose and conducting polymers are the most common materials used in the biosensor interface design.
Journal ArticleDOI

Dye-liquid-crystal-based biosensing for quantitative protein assay

TL;DR: In this paper, an azobenzene dye liquid crystal (DLC) was used for protein detection and quantitation, which exhibited unique optical anisotropy and dichroic absorption at 470 nm.
References
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Journal ArticleDOI

Glucose oxidase-graphene-chitosan modified electrode for direct electrochemistry and glucose sensing

TL;DR: The excellent performance of the biosensor is attributed to large surface-to-volume ratio and high conductivity of graphene, and good biocompatibility of chitosan, which enhances the enzyme absorption and promotes direct electron transfer between redox enzymes and the surface of electrodes.
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Cu3(hexaiminotriphenylene)2: An Electrically Conductive 2D Metal–Organic Framework for Chemiresistive Sensing

TL;DR: Comparison with the isostructural 2D MOF Ni3(HITP)2 shows that the copper sites are critical for ammonia sensing, indicating that rational design/synthesis can be used to tune the functional properties of conductive MOFs.
Journal ArticleDOI

Selective turn-on ammonia sensing enabled by high-temperature fluorescence in metal-organic frameworks with open metal sites.

TL;DR: A heretofore unrecognized, yet potentially general property of many rigid, fluorescent MOFs is described and portend new applications for these materials in selective sensors, with selectivity profiles that can be tuned as a function of temperature.
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