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Integration of ALD tantalum nitride and alpha-phase tantalum for copper metallization application

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TLDR
In this paper, a method for forming a metal interconnect on a substrate is provided, which consists of depositing a refractory metal-containing barrier layer having a thickness less than about 20 angstroms on at least a portion of a metal layer by alternately introducing one or more pulses of metal containing compound and one or multiple pulses of nitrogen containing compound.
Abstract
A method for forming a metal interconnect on a substrate is provided. The method includes depositing a refractory metal-containing barrier layer having a thickness less than about 20 angstroms on at least a portion of a metal layer by alternately introducing one or more pulses of a metal-containing compound and one or more pulses of a nitrogen-containing compound. The method also includes depositing a seed layer on at least a portion of the barrier layer, and depositing a second metal layer on at least a portion of the seed layer. The barrier layer provides adequate barrier properties and allows the grain growth of the metal layer to continue across the barrier layer into the second metal layer thereby enhancing the electrical performance of the interconnect.

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References
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Multiple chamber integrated process system

TL;DR: In this paper, an integrated modular multiple chamber vacuum processing system is described, which includes a load lock, may include an external cassette elevator and an internal load lock wafer elevator, and also includes stations about the periphery of the load lock for connecting one, two or several vacuum process chambers to the load-lock chamber.
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Sequential chemical vapor deposition

TL;DR: In this article, the authors proposed a method for sequential chemical vapor deposition by employing a reactor operated at low pressure, a pump to remove excess reactants, and a line to introduce gas into the reactor through a valve.
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Thermal CVD/PECVD reactor and use for thermal chemical vapor deposition of silicon dioxide and in-situ multi-step planarized process

TL;DR: In this paper, a single wafer, semiconductor processing reactor is described, which is capable of thermal CVD, plasmaenhanced CVD and plasma assisted etchback, plasma self-cleaning, and deposition topography modification by sputtering, either separately or as part of in-situ multiple step processing.
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Atomic layer deposition with nitrate containing precursors

TL;DR: In this paper, metal nitrate-containing precursor compounds are employed in atomic layer deposition processes to form metal-containing films, eg metal, metal oxide, and metal nitride, which films exhibit an atomically abrupt interface and an excellent uniformity.
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Radical-assisted sequential CVD

TL;DR: In this article, a new method for CVD deposition on a substrate is taught wherein radical species are used in alternate steps to depositions from a molecular precursor to treat the material deposited from the molecular precursor and to prepare the substrate surface with a reactive chemical in preparation for the next molecular precursor step.