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Journal ArticleDOI

Kinetic modelling of the pyrolysis of biomass and biomass components

TLDR
In this article, the kinetics of pyrolysis of lignocellulosic materials were studied with a view of providing simple kinetic models for engineering purposes, based on the results obtained by means of thermal analysis techniques.
Abstract
The kinetics of the pyrolysis of lignocellulosic materials was studied with a view of providing simple kinetic models for engineering purposes. Experimental data obtained by means of thermal analysis techniques suggest that the pyrolysis of fine particles (below 1 mm) can be considered to be controlled by pyrolysis kinetics. The rate of pyrolysis of one biomass type can be represented by the sum of the corresponding rates of the main biomass components (cellulose, lignin, hemicellulose). The kinetics of each of these components was simulated by a kinetic scheme capable of predicting the pyrolysis rate and the final weight-loss for a wide range of pyrolysis parameters including various heating conditions.

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Citations
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Journal ArticleDOI

Characteristics of hemicellulose, cellulose and lignin pyrolysis

TL;DR: In this article, the pyrolysis characteristics of three main components (hemicellulose, cellulose and lignin) of biomass were investigated using, respectively, a thermogravimetric analyzer (TGA) with differential scanning calorimetry (DSC) detector and a pack bed.
Journal ArticleDOI

Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review

TL;DR: A review of the recent developments in the wood pyrolysis and reports the characteristics of the resulting bio-oils, which are the main products of fast wood pyrotechnics, can be found in this paper.
Journal ArticleDOI

Lignocellulosic biomass pyrolysis mechanism: A state-of-the-art review

TL;DR: A broad review of the state-of-the-art biomass pyrolysis research can be found in this article, where three major components (cellulose, hemicellulose and lignin) are discussed in detail.
Journal ArticleDOI

Modeling chemical and physical processes of wood and biomass pyrolysis

TL;DR: In this article, the state of the art in modeling chemical and physical processes of wood and biomass pyrolysis is reported, and the main achievements of numerical simulations are discussed.
Journal ArticleDOI

Biomass upgrading by torrefaction for the production of biofuels: A review

TL;DR: An overview of the research on biomass upgrading by torrefaction for the production of biofuels is presented in this article, where the removal of oxygen from biomass aims to produce a fuel with increased energy density by decomposing the reactive hemicellulose fraction.
References
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Journal ArticleDOI

Introduction to pyrolysis of biomass

TL;DR: The pyrolytic properties of biomass are controlled by the chemical composition of its major components, namely cellulose, hemicelluloses and lignin and their minor components including extractives and inorganic materials as mentioned in this paper.
Journal ArticleDOI

Thermal degradation of cellulose in air and nitrogen at low temperatures

TL;DR: This paper showed that at temperatures above 300°C, the rate of pyrolysis is essentially the same in both air and nitrogen, indicating that thermal degradation is independent of the oxidative reactions.
Journal ArticleDOI

Heat transfer and kinetics in the low temperature pyrolysis of solids

TL;DR: In this paper, the relative importance of internal and external heat transfer and of the intrinsic (first order) pyrolysis kinetics can be determined from the Biot number (hR/K).
Journal ArticleDOI

Kinetic investigation of wood pyrolysis

TL;DR: In this paper, the kinetics of wood pyrolysis into gas, tar, and char were investigated in the range of 300 to 400 degrees Celcius at atmospheric pressure.
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