Journal ArticleDOI
New approaches for decarboxylative biaryl coupling
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This article is published in Angewandte Chemie.The article was published on 2007-02-19. It has received 273 citations till now. The article focuses on the topics: Coupling (electronics) & Decarboxylative cross-coupling.read more
Citations
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Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis
Tetsuya Satoh,Masahiro Miura +1 more
TL;DR: Aromatic substrates with oxygen- and nitrogen-containing substituents undergo oxidative coupling with alkynes and alkenes under rhodium catalysis through regioselective C-H bond cleavage, creating fused-ring systems through these reactions.
Journal ArticleDOI
Decarboxylative coupling reactions: a modern strategy for C–C-bond formation
Nuria Rodríguez,Lukas J. Goossen +1 more
TL;DR: This critical review examines transition metal-catalyzed decarboxylative couplings that have emerged within recent years as a powerful strategy to form carbon-carbon or carbon-heteroatom bonds starting from carboxylic acids.
Journal ArticleDOI
Recent advances in aryl–aryl bond formation by direct arylation
TL;DR: Compared to traditional methods, direct arylation affords Ar-Ar compounds in fewer steps by removing the need for prefunctionalisation, and given that either one or two hydrogens are targeted, less waste and good atom economy are features of this methodology.
Journal ArticleDOI
Transition metal-catalyzed direct arylation of substrates with activated sp3-hybridized C-H bonds and some of their synthetic equivalents with aryl halides and pseudohalides.
Fabio Bellina,Renzo Rossi +1 more
TL;DR: New, effective, and more environmentallybenignmethodologiesfortheformation of(cyclo)alkyl-aryl bonds, which require a reduced number of synthetic operations, have emerged as valuable alternatives to the conventional cross-coupling reactions.
Journal ArticleDOI
Catalytic C-C Bond Activations via Oxidative Addition to Transition Metals.
TL;DR: The cleavage and subsequent functionalization of the C-CN bonds and decarbonylation processes operating by an excision of carbon monoxide from ketone derivatives have witnessed a large progress.
References
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Journal ArticleDOI
Palladium-catalyzed cross-coupling reactions of organoboron compounds
Norio Miyaura,Akira Suzuki +1 more
TL;DR: In this paper, a cross-coupling reaction is proposed for coupling 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6.
BookDOI
Metal-catalyzed cross-coupling reactions
TL;DR: In this paper, the authors present an approach to the formation of C-X (X = N, O, S) bonds in metal-catalyzed cross-coupling reactions.
Journal ArticleDOI
Aryl-aryl bond formation one century after the discovery of the Ullmann reaction.
Journal ArticleDOI
The combinatorial synthesis of bicyclic privileged structures or privileged substructures
TL;DR: Privileged substructures are believed to achieve this through the mimicry of common protein surface elements that are responsible for binding, such as β- and gamma;-turns.
Journal ArticleDOI
C-H Bond Functionalization in Complex Organic Synthesis
Kamil Godula,Dalibor Sames +1 more
TL;DR: In this paper, the functionalization of C-H bonds in complex organic substrates catalyzed by transition metal catalysts is studied and the key concepts and approaches aimed at achieving selectivity in complex settings are discussed.
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Carboxylic acids as substrates in homogeneous catalysis.
Decarboxylative coupling reactions: a modern strategy for C–C-bond formation
Nuria Rodríguez,Lukas J. Goossen +1 more