Journal ArticleDOI
Organotin(IV) N,N-disubstituted dithiocarbamates
Flavio Bonati,Renato Ugo +1 more
TLDR
In this article, a discussion as to what physical measurements actually serve as convincing criteria of structure and chelation in dithiocarbamates is presented. But no sure evidence was found for or against the chelation of the dithIocarbamate moiety.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1967-11-01. It has received 466 citations till now. The article focuses on the topics: Dithiocarbamate & Moiety.read more
Citations
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Journal ArticleDOI
Thermochemical parameters of dimethyl and di-iso-propyl dithiocarbamate complexes of palladium(II)
J. Regis Botelho,A. Duarte Gondim,I. M. Garcia dos Santos,P.O. Dunstan,A. G. Souza,Valter J. Fernandes,Antonio S. Araujo +6 more
TL;DR: The standard molar enthalpy of formation of dialkyldithiocarbamate chelates, [Pd(S2CNR2)2], with R=CH3 and i-C3H7, was determined through reaction-solution calorimetry in 1,2-dichloroethane, at 298 K.
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Alkyl Xanthates of Diorg Notin(IV) : Synthesis and Characterization
TL;DR: Alkyl xanthates of diorganotin(IV) have been characterised by elemental and spectral analysis, as well as by molecular weight determination in benzene in which they show monomeric behaviour as discussed by the authors.
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Complex iridium(III) hydrides with dithiocarbamate and xantate groups
A.A. Araneo,T. Napoletano +1 more
TL;DR: In this paper, the first examples of iridium(III) derivatives of dithiocarbamate and xanthate with two sulphur atoms were reported. But the results were limited to those with chelating mononegative ligands having oxygen (β-diketonates) 3 or sulphur (O,O′-dialkyldithiophosphates) 4 as donor atoms.
Journal ArticleDOI
Bis-cyclopentadienyl(methylcyclopentadienyl)N,N-dialkyldithiocarbamato Chloro zirconium(IV) compounds
TL;DR: In this paper, the coordination number 5 was assigned to the zirconium(IV) atom in refluxing dichloromethane, where the dithiocarbamate ligands are bidentate.
Journal ArticleDOI
Synthesis and Characterization of Bismuth(III) bis(Dialkyldithiophosphate)Alkyldithiocarbonate
H. P. S. Chauhan,R. K. Singh +1 more
TL;DR: Displacement reactions of chlorobismuth(III) bis(dialkyldithiophosphates) with potassium alkylditiocarbonates (alkylxanthates) in stoichiometric ratios in benzene/carbondisulfide yield bi
References
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Infrared Spectra of Thioamides and Selenoamides.
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369. Physical properties and chemical constitution. Part XXIII. Miscellaneous compounds. Investigation of the so-called co-ordinate or dative link in esters of oxy-acids and in nitro-paraffins by molecular refractivity determinations. atomic, structural, and group parachors and refractivities
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Synthesis, Structure, and Bonding of Complexes of Dimethyl- and Diphenyltin Ions With Bidentate Ligands1
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Electronic Structures of Dithiocarbamates and Xanthates
TL;DR: It has long been realized that the canonical form (Ia) may contribute significantly to the structure of the dithiocarbamate residue in its complex compounds, M(S2CNR2)n, where M is a metal atom and n its valency.
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Infra-red spectra and structure of some phenyltin compounds
TL;DR: In this paper, the absorption properties of twenty phenyltin compounds have been measured in terms of various structural features in the compounds and the positions of the benzene ring vibrations have been noted together with some analytically useful bands.