Journal ArticleDOI
Organotin(IV) N,N-disubstituted dithiocarbamates
Flavio Bonati,Renato Ugo +1 more
TLDR
In this article, a discussion as to what physical measurements actually serve as convincing criteria of structure and chelation in dithiocarbamates is presented. But no sure evidence was found for or against the chelation of the dithIocarbamate moiety.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1967-11-01. It has received 466 citations till now. The article focuses on the topics: Dithiocarbamate & Moiety.read more
Citations
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Journal ArticleDOI
Dithiocarbamates of dimethylthallium(III). Crystal structure of dimethyl(di-n-propyldithiocarbamato)thallium(III)
José S. Casas,María V. Castaño,Celestino Freire,Agustín Sánchez,José Sordo,Eduardo E. Castellano,Julio Zukerman-Schpector,Julio Zukerman-Schpector +7 more
TL;DR: In this paper, six solid compounds of composition [TlMe2(dtc), where dtc is a dithiocarbamate anion, have been obtained and the main coordination characteristics of these compounds seem to be common to the other compounds, both in the solid state and in solution in CDCl3 or DMSO-d6, to judge by their spectral (IR and NMR) properties.
Journal ArticleDOI
Synthesis and characterization of functionalized dithiocarbamates: New single-source precursors for CdS
TL;DR: In this article, a single-molecular precursors for CdS are prepared by reacting functionalized secondary amine and CS 2 with cadmium acetate dihydrate.
Journal ArticleDOI
Synthesis and characterization of phenoxarsin-10-yl 2-R2N-cyclopent-1-ene-1-carbodithioate (R = H, C2H5, cyclo-C6H11CH2) and the crystal and molecular structure of the 2-amino (R = H) derivative
Raymundo Cea-Olivares,R.A. Toscano,Mirna R. Estrada,Cristian Silvestru,Patricia García y García,Marcela López-Cardoso,Georgina Blass-Amador +6 more
TL;DR: In this paper, a mixture of ACDA 1, 1,1-dithioic acid and N-alkyl derivatives of 2-amino-cyclopent-1,ene-1-carbodithionic acid (ACDA) was obtained by stirring stoichiometric amounts of the reagents in ethanol, over 24 hours at room temperature, at a scale of 2 mmol and yields of the compounds ca 75%.
Journal ArticleDOI
Molecular structure and vibrational spectra of bis-N,N'-diethyldithiocarbamate compounds with closed-shell metal ions
TL;DR: In this paper, the molecular structures of isolated M(Et2dtc)2 (M is ZnII, CdII, HgII, PbII; Et2Dtc is (C2H5)2NC(S)S−) have been examined by the PM3 and MMP2 methods.
Journal ArticleDOI
Thermochemical Properties of Palladium(II) Chelates Involving Dialkyldithiocarbamates
J. R. Botelho,A. G. Souza,Liliane M. Nunes,A. P. Chagas,I. M. Garcia dos Santos,M. M. da Conceição,P.O. Dunstan +6 more
TL;DR: In this paper, the standard molar enthalpies of formation of crystalline dialkyldithiocarbamates chelates were determined through reaction-solution calorimetry in acetone, at 298.15 K.
References
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Infrared Spectra of Thioamides and Selenoamides.
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369. Physical properties and chemical constitution. Part XXIII. Miscellaneous compounds. Investigation of the so-called co-ordinate or dative link in esters of oxy-acids and in nitro-paraffins by molecular refractivity determinations. atomic, structural, and group parachors and refractivities
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Synthesis, Structure, and Bonding of Complexes of Dimethyl- and Diphenyltin Ions With Bidentate Ligands1
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Electronic Structures of Dithiocarbamates and Xanthates
TL;DR: It has long been realized that the canonical form (Ia) may contribute significantly to the structure of the dithiocarbamate residue in its complex compounds, M(S2CNR2)n, where M is a metal atom and n its valency.
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Infra-red spectra and structure of some phenyltin compounds
TL;DR: In this paper, the absorption properties of twenty phenyltin compounds have been measured in terms of various structural features in the compounds and the positions of the benzene ring vibrations have been noted together with some analytically useful bands.