Journal ArticleDOI
Organotin(IV) N,N-disubstituted dithiocarbamates
Flavio Bonati,Renato Ugo +1 more
TLDR
In this article, a discussion as to what physical measurements actually serve as convincing criteria of structure and chelation in dithiocarbamates is presented. But no sure evidence was found for or against the chelation of the dithIocarbamate moiety.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1967-11-01. It has received 466 citations till now. The article focuses on the topics: Dithiocarbamate & Moiety.read more
Citations
More filters
Journal ArticleDOI
Synthesis, characterization and the use of organotin(IV) dithiocarbamate complexes as precursor to tin sulfide nanoparticles by heat up approach
TL;DR: In this paper, the reactions of dimethyltin(IV)chloride with different N-alkyl-N-phenyl dithiocarbamate ligands in 1 1/mol equivalence yielded complexes of the type [(CH3)2SnL1L3] (1) and [(CH 3)2snL2L3], where (alkyl) = methyl (L1), ethyl= (L2) and butyl (L3) were characterized using spectroscopic techniques (FTIR, 1H, 13C and 119
Journal ArticleDOI
Preparation and characterization of some stereochemically rigid seven coordinate monocyclopentadienyl zirconium(IV) tris-alkyl xanthate complexes
TL;DR: In this paper, the reaction of dicyclopentadienyl zirconium(IV) dichloride with sodium alkyl xanthates in aqueous medium was investigated.
Journal ArticleDOI
Bis(N-benzyl-N-furfuryldithiocarbamato-S,S′)mercury(II) as a precursor for the preparation of mercury sulfide nanoparticles
Govindaraju Gomathi,Sajad Hussain Dar,Subbiah Thirumaran,Samuele Ciattini,Sivashanmugam Selvanayagam +4 more
TL;DR: In this article, a single-crystal X-ray structure of the thioureide (N 13 CS 2 ) carbon signals were observed at 206.8 and 206.7ppm for 1 and 2, respectively, with very weak intensity, characteristic of the quaternary carbon signal.
Journal ArticleDOI
Synthesis and structure of some triphenyltin(IV) dithiocarbamate compounds
TL;DR: In this paper, a low temperature synthesis is described for the preparation of organotin dithiocarbamate compounds (including N -cyclic and N -monosubstituted derivatives) in which the products have low levels of the usual sulfide impurities.
Journal ArticleDOI
Syntheses, spectral characterization, X-ray studies and in vitro cytotoxic activities of triorganotin(IV) derivatives of p-substituted N-methylbenzylaminedithiocarbamates
TL;DR: In this paper, two new organotin(IV) complexes of the type R3SnL were synthesized in 1:1molar ratio with good yields and isolated as crystalline solids.
References
More filters
Journal ArticleDOI
Infrared Spectra of Thioamides and Selenoamides.
Journal ArticleDOI
369. Physical properties and chemical constitution. Part XXIII. Miscellaneous compounds. Investigation of the so-called co-ordinate or dative link in esters of oxy-acids and in nitro-paraffins by molecular refractivity determinations. atomic, structural, and group parachors and refractivities
Journal ArticleDOI
Synthesis, Structure, and Bonding of Complexes of Dimethyl- and Diphenyltin Ions With Bidentate Ligands1
Journal ArticleDOI
Electronic Structures of Dithiocarbamates and Xanthates
TL;DR: It has long been realized that the canonical form (Ia) may contribute significantly to the structure of the dithiocarbamate residue in its complex compounds, M(S2CNR2)n, where M is a metal atom and n its valency.
Journal ArticleDOI
Infra-red spectra and structure of some phenyltin compounds
TL;DR: In this paper, the absorption properties of twenty phenyltin compounds have been measured in terms of various structural features in the compounds and the positions of the benzene ring vibrations have been noted together with some analytically useful bands.