Journal ArticleDOI
Organotin(IV) N,N-disubstituted dithiocarbamates
Flavio Bonati,Renato Ugo +1 more
TLDR
In this article, a discussion as to what physical measurements actually serve as convincing criteria of structure and chelation in dithiocarbamates is presented. But no sure evidence was found for or against the chelation of the dithIocarbamate moiety.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1967-11-01. It has received 466 citations till now. The article focuses on the topics: Dithiocarbamate & Moiety.read more
Citations
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Reactivity of Mixed Ligand Complexes I. Interaction of Dithizonato-Alkylxanthato Nickel(II) with 2,2′-Bipyridyl and 1,10-o-Phenanthroline
Asma I. El-Said,Aref A. M. Aly +1 more
TL;DR: In this paper, a series of new ionic, mixed ligand complexes has been synthesized and characterized, and an octahedral structure around Ni(II) was suggested from the thermal analysis.
Journal ArticleDOI
Synthesis, Structural and Biological Studies of Organotin(IV) Complexes with N-(Dithiocarboxy) Sarcosine
Shabbir Hussain,Saqib Ali,Saira Shahzadi,Muhammad Riaz,Khalida Nazir,Muhammad Nadeem Arshad,Abdullah M. Asiri +6 more
TL;DR: In this paper, five organotin complexes with general formulae were synthesized by the reaction of equimolar quantities of sarcosine (HLH) with KOH, CS2 and either R2SnCl2 (R = Me, n-Bu, Ph) or R3SnCl (R͡= ͡n-Bu, Ph) in methanol.
Journal ArticleDOI
Thermochemical parameters of complexes of di-n-propyldithiocarbamate of phosphorus-group elements
TL;DR: In this article, the standard molar enthalpy of di-n-propyldithiocarbamate complexes of P, As, Sb and Bi(III) was determined through reaction-solution calorimetry in acetone, at 298.15 K, giving −661.10±5.04, −305.62±1.70 and −358.98±1, respectively.
Journal ArticleDOI
Über Chalkogenolate. 193. S-Bis(trimethylsilyl)aminoester von Dithiocarbamidsäuren 2. Spektroskopische Charakterisierung
G. Schubert,G. Gattow +1 more
TL;DR: In this paper, the free activation energy of the rotation barrier around the NCS bond is measured at −2°C (coalescence temperature), and the coupling constants have been determined (data see „Inhaltsubersicht”).
Journal ArticleDOI
Synthesis, spectral and antibacterial studies on Ni(II) and Zn(II) complexes involving N-furfuryl-N-isopropyldithiocarbamate (f iprdtc) and Lewis bases: X-ray structure of [Ni(f iprdtc)(NCS)(PPh3)]
TL;DR: In this article, a single-crystal X-ray structural analysis of 2 proved four-coordinated nickel in a distorted square planar arrangement with a S2PN donor set.
References
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Infrared Spectra of Thioamides and Selenoamides.
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369. Physical properties and chemical constitution. Part XXIII. Miscellaneous compounds. Investigation of the so-called co-ordinate or dative link in esters of oxy-acids and in nitro-paraffins by molecular refractivity determinations. atomic, structural, and group parachors and refractivities
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Synthesis, Structure, and Bonding of Complexes of Dimethyl- and Diphenyltin Ions With Bidentate Ligands1
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Electronic Structures of Dithiocarbamates and Xanthates
TL;DR: It has long been realized that the canonical form (Ia) may contribute significantly to the structure of the dithiocarbamate residue in its complex compounds, M(S2CNR2)n, where M is a metal atom and n its valency.
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Infra-red spectra and structure of some phenyltin compounds
TL;DR: In this paper, the absorption properties of twenty phenyltin compounds have been measured in terms of various structural features in the compounds and the positions of the benzene ring vibrations have been noted together with some analytically useful bands.