Journal ArticleDOI
Organotin(IV) N,N-disubstituted dithiocarbamates
Flavio Bonati,Renato Ugo +1 more
TLDR
In this article, a discussion as to what physical measurements actually serve as convincing criteria of structure and chelation in dithiocarbamates is presented. But no sure evidence was found for or against the chelation of the dithIocarbamate moiety.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1967-11-01. It has received 466 citations till now. The article focuses on the topics: Dithiocarbamate & Moiety.read more
Citations
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Studies on novel functional β-cyclodextrin and its metal complexes
TL;DR: In this paper, a partially substituted dithiocarboxyl β-cyclodextrin and its metal complexes were synthesized and characterized by means of IR, UV, 1 H NMR, MS, electron spin resonance, cyclic voltammetry and transmission electron microscope.
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CHARACTERIZATION OF [μ-BIS(DIPHENYLPHOSPHINO)ALKANE] BIS[N,N-DIALKYLDITHIOCARBAMATO)GOLD(I)] COMPLEXES: X-RAY CRYSTAL STRUCTURE OF [(Ph2P(CH2)2PPh2)(AuS2CNEt2)2]
TL;DR: In this paper, the preparation and spectroscopic characterization of six compounds of general formula (Ph2P(CH2)nPPh2)(AuS2CNR2)2], n = 1, 2 or 3 and R = Et or c-hexyl, is reported.
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Metal—sulphur bond enthalpy determination of diethyldithiocarbamate complexes of cadmium and mercury
TL;DR: In this article, the standard molar enthalpy of formation of crystalline diethyldithiocarbamate complexes of Cd and Hg(II) has been derived by solution calorimetry at 298.15 K, giving −227.5 ± 5.0 and −141.4 ± 6.0 kJ mol −1, respectively.
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Synthesis and Characterization of Some Toluene‐3,4‐dithiolatobismuth(III) Alkyl Dithiocarbonates
TL;DR: Some mixed toluene−3,4−dithiolatobismuth(III) alkyl dithiocarbonate derivatives of the type (where R = {Me, Et, n−Pr, i•Pr, n•Bu, and i•Bu} have been synthesized by the reaction of the potassium salts of alkyls dithIocarbonates and toluenes−3−4−dimethyldithIoBismuth (III) chloride in equimolar ratio in an anhydrous carbon disulfide
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Synthesis, characterization and in vitro cytotoxicity of palladium(II) complexes with mixed ligands: X-ray diffraction study of C31H36ClNPPdS2
TL;DR: The cytotoxicity of compounds 2, 3 and 4 was determined in vitro against six human tumour cell lines, and compounds 1–6 possess antifungal activity against Fusarium moniliformes, FUSarium saolani, Mucor sp.
References
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Infrared Spectra of Thioamides and Selenoamides.
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369. Physical properties and chemical constitution. Part XXIII. Miscellaneous compounds. Investigation of the so-called co-ordinate or dative link in esters of oxy-acids and in nitro-paraffins by molecular refractivity determinations. atomic, structural, and group parachors and refractivities
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Synthesis, Structure, and Bonding of Complexes of Dimethyl- and Diphenyltin Ions With Bidentate Ligands1
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Electronic Structures of Dithiocarbamates and Xanthates
TL;DR: It has long been realized that the canonical form (Ia) may contribute significantly to the structure of the dithiocarbamate residue in its complex compounds, M(S2CNR2)n, where M is a metal atom and n its valency.
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Infra-red spectra and structure of some phenyltin compounds
TL;DR: In this paper, the absorption properties of twenty phenyltin compounds have been measured in terms of various structural features in the compounds and the positions of the benzene ring vibrations have been noted together with some analytically useful bands.