Journal ArticleDOI
Organotin(IV) N,N-disubstituted dithiocarbamates
Flavio Bonati,Renato Ugo +1 more
TLDR
In this article, a discussion as to what physical measurements actually serve as convincing criteria of structure and chelation in dithiocarbamates is presented. But no sure evidence was found for or against the chelation of the dithIocarbamate moiety.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1967-11-01. It has received 466 citations till now. The article focuses on the topics: Dithiocarbamate & Moiety.read more
Citations
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Carbodithioato derivatives of weak nitrogenous nucleophiles II. Non-direct syntheses and structural studies of Ni(II) N-carbodithioates with substituted ureas, carbamic esters and sulfonamides
TL;DR: In this paper, the authors reported the isolation of nickel(II) complexes of the type Ni[S 2 CN(E)R] 2, (E = electrophile), and their characterization by chemical analysis, as well as magnetic and spectral studies.
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Mixed-ligand iron(III) dithiocarbamates. Calculation of ligand field parameters in electron spin crossover d5 systems by combination of spectral and magnetic data
TL;DR: In this article, a mixed-ligand iron(III) dithiocarbamate complexes of the general formula Fe(R 2 dtc) 2 [R 2 Dtc] have been prepared and characterized.
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Synthesis and characterization of metal dithiocarbamate derivatives of 3-((pyridin-2-yl)methylamino)propanenitrile: Crystal structure of [3-((pyridin-2-yl)methylamino)propanenitrile dithiocarbamato] nickel(II)
TL;DR: In this paper, four metal dithiocarbamate complexes (Zn, Ni, Hg and Sn) based on an amine containing pyridyl and nitrile groups, 3-((pyridin-2-ylmethylamino)propanenitrile, were prepared and characterized by their elemental analysis, spectroscopic data (such as IR, 1H and 13C NMR), TGA analysis and X-ray crystallography of the Ni(II) complex.
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Dithiocarbamate copper(I) and silver(I) complexes: Synthesis, structure and thermal behavior
TL;DR: In this paper, the molecular structures of 12a,b in the solid state are reported confirming the monomeric architecture with coordination number 4 at silver, which is setup by a chelate-bonded S2CNR(C2H4OH) unit and two coordinated PPh3 ligands.
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In vitro biological studies of heteroleptic Ag(I) and Cu(I) unsymmetrical N,N′-diarylformamidine dithiocarbamate phosphine complexes; the effect of the metal center
TL;DR: A series of five dithiocarbamate and their respective Ag(I) and Cu(I)-triphenylphosphine complexes of the general formula [Ag/Cu(PPh3)2L] were synthesized and characterized as discussed by the authors.
References
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Infrared Spectra of Thioamides and Selenoamides.
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369. Physical properties and chemical constitution. Part XXIII. Miscellaneous compounds. Investigation of the so-called co-ordinate or dative link in esters of oxy-acids and in nitro-paraffins by molecular refractivity determinations. atomic, structural, and group parachors and refractivities
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Synthesis, Structure, and Bonding of Complexes of Dimethyl- and Diphenyltin Ions With Bidentate Ligands1
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Electronic Structures of Dithiocarbamates and Xanthates
TL;DR: It has long been realized that the canonical form (Ia) may contribute significantly to the structure of the dithiocarbamate residue in its complex compounds, M(S2CNR2)n, where M is a metal atom and n its valency.
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Infra-red spectra and structure of some phenyltin compounds
TL;DR: In this paper, the absorption properties of twenty phenyltin compounds have been measured in terms of various structural features in the compounds and the positions of the benzene ring vibrations have been noted together with some analytically useful bands.