Journal ArticleDOI
Palladium-catalysed cross-coupling of organosilicon reagents
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The palladium catalysed cross-coupling of organosilicon reagents with organo halides and pseudo-halides has developed over the past 30 years into an efficient and attractive carbon-carbon bond forming strategy.Abstract:
The palladium catalysed cross-coupling of organosilicon reagents with organo halides and pseudo-halides has developed over the past 30 years into an efficient and attractive carbon–carbon bond forming strategy. Extensive research within this field to expand and diversify on the scope of the organosilicon coupling reaction will continue to promote its use in the synthesis of biologically and pharmaceutically important organic molecules. The recent advances made within this area are explored in this critical review (199 references).read more
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Transition-Metal-Free Coupling Reactions
TL;DR: This research presents a new generation of state-of-the-art materials for bioorganic and non-volatile organometallic research that combines high-performance liquid chromatography and high-tech materials for organic synthesis.
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Recent Advances in Transition-Metal-Catalyzed Synthetic Transformations of Organosilicon Reagents
TL;DR: In this article, a cross-coupling of organosilicon reagents with organic halides or pseudohalides has been considered to be a useful tool for constructing the carbon frameworks of various target molecules such as pharmaceuticals and π-conjugated functional materials.
Journal ArticleDOI
Colourimetric and fluorescent probes for the optical detection of palladium ions.
TL;DR: This review provides a brief introduction to the new methods used to determine trace amounts of Pd(2+), which mainly focuses on the different reporting systems and unique mechanisms of the colourimetric and fluorescent probes used to detect Pd (2+) complex formation or Pd-catalysed reactions.
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Visible Light-Induced Room-Temperature Heck Reaction of Functionalized Alkyl Halides with Vinyl Arenes/Heteroarenes.
TL;DR: The first visible light-induced Pd-catalyzed Heck reaction of α-heteroatom substituted alkyl iodides and -bromides with vinyl arenes/heteroarenes has been developed and enables synthesis of valuable functionalized allylic systems.
Journal ArticleDOI
Boron-Catalyzed Aromatic C–H Bond Silylation with Hydrosilanes
TL;DR: Metal-free catalytic C-H silylation of a series of aromatic compounds such as N,N-disubstituted anilines with various hydrosilanes with various hydrogen acceptors has been achieved for the first time using commercially available B(C6F5)3 as a catalyst.
References
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Journal ArticleDOI
Palladium-catalyzed cross-coupling reactions of organoboron compounds
Norio Miyaura,Akira Suzuki +1 more
TL;DR: In this paper, a cross-coupling reaction is proposed for coupling 1 -Alkenylboron Derivatives: Synthesis of Conjugated Dienes 6.
BookDOI
Metal-catalyzed cross-coupling reactions
TL;DR: In this paper, the authors present an approach to the formation of C-X (X = N, O, S) bonds in metal-catalyzed cross-coupling reactions.
Journal ArticleDOI
The Palladium‐Catalyzed Cross‐Coupling Reactions of Organotin Reagents with Organic Electrophiles [New Synthetic Methods (58)]
TL;DR: The cross-coupling of organotin reagents with a variety of organic electrophiles, catalyzed by palladium, provides a novel method for generating a carbon-carbon bond.
Journal ArticleDOI
Recent advances in the cross-coupling reactions of organoboron derivatives with organic electrophiles, 1995–1998
TL;DR: The palladium-catalyzed cross-coupling reaction between organoboron compounds and organic halides or triflates provides a powerful and general methodology for the formation of carbon-carbon bonds as discussed by the authors.
Journal ArticleDOI
Palladium-catalyzed cross-coupling reactions in total synthesis.
TL;DR: In this Review, highlights of a number of selected syntheses are discussed, demonstrating the enormous power of these processes in the art of total synthesis and underscore their future potential in chemical synthesis.
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