Journal ArticleDOI
Polymerization of thiophene containing cyclobutadiene Co cyclopentadiene complexes
TLDR
In this article, a series of cyclobutadiene cobalt cyclopentadiene (CbCoCp) complexes containing electrochemically polymerizable thiophene units were synthesized.About:
This article is published in Synthetic Metals.The article was published on 2006-06-01. It has received 11 citations till now. The article focuses on the topics: Cyclobutadiene & Thiophene.read more
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Organometallic Electrochemistry: Origins, Development, and Future
TL;DR: In this article, the evolution of organotransition metal electrochemistry from its origin with ferrocene to its promise in future applications is presented, where key findings on the relationships of electron transfer to molecular structures and to the reactions of OMT metal complexes are given.
Journal ArticleDOI
Metal-containing Polymers via Electropolymerization
TL;DR: Recent developments in the field of synthesis and potential applications of metal-functionalized polymers obtained via electropolymerization are presented, highlighting the significant advances in this field of research.
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Metallomacromolecules containing cobalt sandwich complexes: Synthesis and functional materials properties
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Side chain Co(I) polymers featuring acrylate functionalized neutral 18 electron CpCo(C4R4) (R=Ph, Me) units.
Preeti Chadha,Paul J. Ragogna +1 more
TL;DR: Acrylate derivatives of these compounds were found to polymerize giving rise to the first example of polymers containing neutral, 18 e cobaltoarenocenes in the side chain.
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Reflections on Future Directions in Organometallic Electrochemistry
TL;DR: In this paper, the authors employed both as an analytical instrumental technique and as a method of inducing changes in the structure and reactivity of organometallic complexes, which is the primary implemen...
References
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Journal ArticleDOI
A simple two-band electrode for in situ conductivity measurements of polyconjugated conducting polymers
TL;DR: In this paper, a simple and renewable two-band electrode for in situ determination of electronic conductivity in polyconjugated polymers is described, and the electrode was tested with electrodeposited polypyrrole, poly- N -methylpyrdrug, polyaniline and poly-3-methylthiophene.
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Transition‐Metal–Polythiophene Hybrid Materials
TL;DR: In this paper, the properties of monomers containing transition metals and thiophene are reviewed and polymers with metal centers linked to the backbone via a saturated linker (Type I), closely coupled to the conjugated backbone and directly in the backbone (Type III) are described.
Journal ArticleDOI
Dipolar and Nonpolar Altitudinal Molecular Rotors Mounted on an Au(111) Surface
Xiaolai Zheng,Mary E. Mulcahy,Dominik Horinek,Francesco Galeotti,Thomas F. Magnera,Josef Michl +5 more
TL;DR: A compound whose molecules consist of two metal sandwich stands carrying tentacles with affinity to metal surfaces and holding an axle that carries a dipolar or a nonpolar rotator that is characterized by several spectroscopic and imaging techniques is described.
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Three-Step Redox in Polythiophenes: Evidence from Electrochemistry at an Ultramicroelectrode
Xiwen Chen and,Olle Inganäs +1 more
TL;DR: In this article, the transition between polaron, bipolaron, and metallic states of poly(3,4-ethylenedioxythiophene) (PEDOT) was detected using in situ UV−VIS−NIR spectroscopy.
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Solitons in a box: The organic chemistry of electrically conducting polyenes
TL;DR: In this article, the authors provide a general exposition of the principles underlying electrical conductivity in organic polymers which, unlike previous more extensive treatments, develops a connection between the bulk material properties and properties of discrete organic molecules.