Journal ArticleDOI
Porous homo- and heterochiral cobalt(II) aspartates with high thermal stability of the metal-organic framework
Maxim P. Yutkin,M. S. Zavakhina,Denis G. Samsonenko,Denis G. Samsonenko,Danil N. Dybtsev,Vladimir P. Fedin,Vladimir P. Fedin +6 more
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TLDR
In this article, metal-organic coordination polymers with the compositions [Co2(L-asp) 2-(bpy)] · MeOH · H2O (1), [Co 2(Lasp)2(bpe)] · 0.28 (bpe) · H 2O (2), and [Co(d-asp)(l-asp)-(bpa)]· 0.25 (bpa) · 1.5H2O(3) (H2asp is aspartic acid, bpy is 4,4′-bAbstract:
Metal-organic coordination polymers with the compositions [Co2(L-asp) 2-(bpy)] · MeOH · H2O (1), [Co2(L-asp)2(bpe)] · 0.28(bpe) · H2O (2), and [Co2(d-asp)(l-asp)-(bpa)] · 0.25(bpa) · 1.5H2O (3) (H2asp is aspartic acid, bpy is 4,4′-bipyridine, bpe is trans-bis(4- pyridyl)ethylene, and bpa is 1,2-bis(4-pyridyl)ethane) were synthesized on heating cobalt(II) as-partate and N-donor ligands (bpy, bpe, or bpa) in an aqueous-methanol mixture. The structures of compounds 1⁗ash;3 were established by X-ray diffraction analysis and confirmed by X-ray powder crystallography, IR spectroscopy, thermogravimetry, and elemental analysis. The stability of the synthesized coordination polymers was studied. It was shown that they retain the framework structure on heating to 300 °C.read more
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A review on metal-organic frameworks: Synthesis and applications
Mohadeseh Safaei,Mohammad Mehdi Foroughi,Nasser Ebrahimpoor,Shohreh Jahani,Ali Omidi,Mehrdad Khatami +5 more
TL;DR: The use of metal organic frameworks in different fields such as the removal of absorption and separation of toxic substances from gas and liquid, catalysts, a variety of sensors, storage of clean energies and environmental applications, medical and biological applications, and optoelectronic equipment is included as discussed by the authors.
Journal ArticleDOI
Metal-organic frameworks: structure, properties, methods of synthesis and characterization
Vera V. Butova,Mikhail A. Soldatov,Alexander A. Guda,Kirill A. Lomachenko,Kirill A. Lomachenko,Carlo Lamberti,Carlo Lamberti +6 more
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Chiral Metal-Organic Frameworks.
TL;DR: A recent review of metal-organic frameworks (MOFs) can be found in this paper , which summarizes the recent progress of CMOFs regarding design strategies, synthetic approaches, and cutting-edge applications.
Journal ArticleDOI
Chiral metal–organic frameworks based on asymmetric synthetic strategies and applications
TL;DR: In this article, a comprehensive review of chiral metal-organic frameworks (CMOFs) is presented, which includes preparation methods, collection of CMOFs with peculiar properties, and various asymmetric applications along with recent developments of the CMOF family.
Journal ArticleDOI
Homochiral Cu(II) and Ni(II) malates with tunable structural features
M. S. Zavakhina,Denis G. Samsonenko,Denis G. Samsonenko,Alexander V. Virovets,Danil N. Dybtsev,Danil N. Dybtsev,Vladimir P. Fedin,Vladimir P. Fedin +7 more
TL;DR: In this article, four new homochiral metal-organic frameworks (MOFs) based on S-malate anions and N-donor linkers of different length have been prepared under solvothermal conditions.
References
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A homochiral metal-organic porous material for enantioselective separation and catalysis
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A Homochiral Porous Metal−Organic Framework for Highly Enantioselective Heterogeneous Asymmetric Catalysis
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