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Journal ArticleDOI

Recent developments of ketene dithioacetal chemistry.

Ling Pan, +2 more
- 16 Jan 2013 - 
- Vol. 42, Iss: 3, pp 1251-1286
TLDR
This review aims to provide an intrinsic link between ketene dithioacetal groups and a variety of other functional groups, which has brought out many new facts that will assist in future designs.
Abstract
Ketene dithioacetals are versatile intermediates in organic synthesis. Extensive research, since the last decade, has given rise to new prospects in their chemistry. The objective of this review is twofold: first, to highlight the new prospects in the chemistry of functionalized ketene dithioacetals, and second, to provide an intrinsic link between ketene dithioacetal groups and a variety of other functional groups, which has brought out many new facts that will assist in future designs.

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Citations
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Journal ArticleDOI

Transition-metal mediated carbon-sulfur bond activation and transformations: an update.

TL;DR: This review summarizes the advances in transition-metal-catalyzed cross-coupling via carbon-sulfur bond activation and cleavage since late 2012 as an update of the critical review on the same topic published in early 2013.
Journal ArticleDOI

Metal-free domino one-pot protocols for quinoline synthesis

TL;DR: All contributions till March 2015 are surveyed with particular emphasis on metal-free domino reactions for quinoline ring construction and are discussed herein along with mechanistic aspects.
Journal ArticleDOI

Chemistry of Ketene N,S-Acetals: An Overview.

TL;DR: This review provides comprehensive knowledge on the chemistry of ketene N,S-acetals, which make them versatile and easy to use, especially in cyclization and multicomponent reactions for the synthesis of various heterocyclic systems and related natural products.
Journal ArticleDOI

Chemoselective cross-coupling reaction of sodium sulfinates with phenols under aqueous conditions

TL;DR: An efficient procedure for the formation of C–S bonds via direct C–H functionalization has been developed under aqueous conditions and a broad range of functional groups were well tolerated in this reaction system.
References
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Journal ArticleDOI

Towards mild metal-catalyzed C–H bond activation

TL;DR: This critical review summarizes and discusses endeavours towards the development of mild C-H activation methods and wishes to trigger more research towards this goal.
Journal ArticleDOI

Chemistry and Biology Of Multicomponent Reactions

TL;DR: This paper presents a new approach to drug design called “combinatorial biosynthesis and drug discovery through nanofiltration”, which combines the efforts of a single investigator with those of a number of other scientists.
Journal ArticleDOI

Catalysis for fluorination and trifluoromethylation

TL;DR: Reactions to make organofluorides that have emerged within the past few years are discussed and which exemplify how to overcome some of the intricate challenges associated with fluorination.
Journal ArticleDOI

Aromatic Trifluoromethylation with Metal Complexes

TL;DR: Molecules bearing a trifluoromethyl group constitute one of the most important classes of selectively fluorinated compounds, and derivatives bearing the CF3 group on aromatic rings are particularly numerous and important.
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