Journal ArticleDOI
Stable Large-Area (10 × 10 cm2) Printable Mesoscopic Perovskite Module Exceeding 10% Efficiency
Yue Hu,Si Si,Anyi Mei,Yaoguang Rong,Huawei Liu,Xiong Li,Hongwei Han +6 more
- Vol. 1, Iss: 2, pp 1600019
TLDR
In this article, a hole-conductor-free printable perovskite solar module is demonstrated, which employs a triple layer of mesoporous TiO2/ZrO2 /carbon as scaffold, and is infiltrated by a mixed cation lead halide perovskiite (5-AVA)x(MA)1−xPbI3 as a light harvester.Abstract:
The commercial manufacturing of perovskite solar modules (PSM) suffers from stability concerns and scalability issues. We demonstrate a hole-conductor-free printable solar module embodiment, which employs a triple layer of mesoporous TiO2/ZrO2/carbon as scaffold, and is infiltrated by a mixed cation lead halide perovskite (5-AVA)x(MA)1−xPbI3 as a light harvester. Here, hole conductor or Au reflector are not employed, and instead, the back contact comprises simply a printed carbon layer. Upon optimizing the thickness alignment of the triple mesoscopic layer and the design of the active area, the unit cell shows 14.02% power conversion efficiency (PCE) under 100 mW cm−2 condition, while a larger area of 10 serially connected cells module (10 × 10 cm2), shows a 10.4% PCE on an active area of 49 cm2. Light-soaking stability of 1000 h has been demonstrated, as well as local outdoor stability of 1 month and a shelf-life stability of over 1 year. This paves the way for the realization of efficient and stable large-area PSMs for industrial deployment.read more
Citations
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Journal ArticleDOI
Halide Perovskite Photovoltaics: Background, Status, and Future Prospects
TL;DR: The fundamentals, recent research progress, present status, and views on future prospects of perovskite-based photovoltaics, with discussions focused on strategies to improve both intrinsic and extrinsic (environmental) stabilities of high-efficiency devices are described.
Journal ArticleDOI
Challenges for commercializing perovskite solar cells.
Yaoguang Rong,Yue Hu,Anyi Mei,Anyi Mei,Hairen Tan,Hairen Tan,Makhsud I. Saidaminov,Sang Il Seok,Michael D. McGehee,Edward H. Sargent,Hongwei Han +10 more
TL;DR: Recent progress in addressing stability, how to allow mass production, and how to maintain uniformity of large-area films are reviewed, and the remaining challenges along the pathway to their commercialization are discussed.
Journal ArticleDOI
Understanding Degradation Mechanisms and Improving Stability of Perovskite Photovoltaics.
Caleb C. Boyd,Rongrong Cheacharoen,Rongrong Cheacharoen,Tomas Leijtens,Tomas Leijtens,Michael D. McGehee,Michael D. McGehee +6 more
TL;DR: Recommendations are made on how accelerated testing should be performed to rapidly develop solar cells that are both extraordinarily efficient and stable.
Journal ArticleDOI
Scalable fabrication of perovskite solar cells
Zhen Li,Talysa R. Klein,Dong Hoe Kim,Mengjin Yang,Joseph J. Berry,Maikel F.A.M. van Hest,Kai Zhu +6 more
TL;DR: In this paper, the authors review recent progress and challenges in scaling up perovskite solar cells and related efforts to enable the terawatt-scale manufacturing and deployment of this PV technology.
Journal ArticleDOI
A solvent- and vacuum-free route to large-area perovskite films for efficient solar modules
Han Chen,Fei Ye,Wentao Tang,Jinjin He,Maoshu Yin,Yanbo Wang,Fengxian Xie,Enbing Bi,Xudong Yang,Michael Grätzel,Liyuan Han,Liyuan Han +11 more
TL;DR: A new deposition route for methyl ammonium lead halide perovskite films that does not rely on use of a common solvent or vacuum, and relies on the rapid conversion of amine complex precursors to perovkite films, followed by a pressure application step to overcome the substantial reduction in power conversion efficiency when a small device is scaled up.
References
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Journal ArticleDOI
High-performance photovoltaic perovskite layers fabricated through intramolecular exchange
Woon Seok Yang,Jun Hong Noh,Nam Joong Jeon,Young Chan Kim,Seungchan Ryu,Jangwon Seo,Sang Il Seok +6 more
TL;DR: An approach for depositing high-quality FAPbI3 films, involving FAP bI3 crystallization by the direct intramolecular exchange of dimethylsulfoxide (DMSO) molecules intercalated in PbI2 with formamidinium iodide is reported.
Journal ArticleDOI
Compositional engineering of perovskite materials for high-performance solar cells
Nam Joong Jeon,Jun Hong Noh,Woon Seok Yang,Young Chan Kim,Seungchan Ryu,Jangwon Seo,Sang Il Seok +6 more
TL;DR: This work combines the promising—but relatively unstable formamidinium lead iodide with FAPbI3 with methylammonium lead bromide as the light-harvesting unit in a bilayer solar-cell architecture and improves the power conversion efficiency of the solar cell to more than 18 per cent under a standard illumination.
Journal ArticleDOI
A hole-conductor-free, fully printable mesoscopic perovskite solar cell with high stability
Anyi Mei,Xiong Li,Linfeng Liu,Zhiliang Ku,Tongfa Liu,Yaoguang Rong,Mi Xu,Min Hu,Jiangzhao Chen,Ying Yang,Michael Grätzel,Hongwei Han +11 more
TL;DR: A perovskite solar cell that uses a double layer of mesoporous TiO2 and ZrO2 as a scaffold infiltrated with perovSkite and does not require a hole-conducting layer is fabricated and achieves a certified power conversion efficiency of 12.8%.
Journal ArticleDOI
Efficient and stable large-area perovskite solar cells with inorganic charge extraction layers
Wei Chen,Wei Chen,Yongzhen Wu,Youfeng Yue,Jian Liu,Wenjun Zhang,Xudong Yang,Han Chen,Enbing Bi,Islam Ashraful,Michael Grätzel,Liyuan Han,Liyuan Han +12 more
TL;DR: Heavy doped inorganic charge extraction layers in planar PSCs were used to achieve very rapid carrier extraction, even with 10- to 20-nanometer-thick layers, avoiding pinholes and eliminating local structural defects over large areas.
Journal ArticleDOI
The light and shade of perovskite solar cells
TL;DR: The rise of metal halide perovskites as light harvesters has stunned the photovoltaic community and questions on the control of the performance of perovSKite solar cells and on its characterization are being addressed.