Strategies to Improve the Energy Storage Properties of Perovskite Lead-Free Relaxor Ferroelectrics: A Review
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TLDR
Some of the main strategies to improve the energy density properties of perovskite lead-free relaxor systems are reviewed, including chemical modification at different crystallographic sites, chemical additives that do not target lattice sites, and novel processing approaches dedicated to bulk ceramics, thick and thin films, respectively.Abstract:
Electrical energy storage systems (EESSs) with high energy density and power density are essential for the effective miniaturization of future electronic devices. Among different EESSs available in the market, dielectric capacitors relying on swift electronic and ionic polarization-based mechanisms to store and deliver energy already demonstrate high power densities. However, different intrinsic and extrinsic contributions to energy dissipations prevent ceramic-based dielectric capacitors from reaching high recoverable energy density levels. Interestingly, relaxor ferroelectric-based dielectric capacitors, because of their low remnant polarization, show relatively high energy density and thus display great potential for applications requiring high energy density properties. In this study, some of the main strategies to improve the energy density properties of perovskite lead-free relaxor systems are reviewed, including (i) chemical modification at different crystallographic sites, (ii) chemical additives that do not target lattice sites, and (iii) novel processing approaches dedicated to bulk ceramics, thick and thin films, respectively. Recent advancements are summarized concerning the search for relaxor materials with superior energy density properties and the appropriate choice of both composition and processing routes to match various applications' needs. Finally, future trends in computationally-aided materials design are presented.read more
Citations
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Superior energy storage performance in (Bi0.5Na0.5)TiO3-based lead-free relaxor ferroelectrics for dielectric capacitor application via multiscale optimization design
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Progress on Emerging Ferroelectric Materials for Energy Harvesting, Storage and Conversion
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TL;DR: In this paper , the authors proposed a surrogate approach by A-site defect engineering in (Bi0.47Sm 0.03Na 0.5-x)0.94Ba0.5TiO3 (BNT) with large polarization and Aurivillius phases of BaBi4Ti4O15 (BBT) generation high breakdown electric field.
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