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Superconductivity in HEA-Type Compounds

TLDR
In this article, the effects of the introduction of a HEA site in various kinds of complicated compounds are discussed from the structuraldimensionality viewpoint, including NaCl-type metal tellurides, CuAl2-type transition metal zirconides, high-Tc cuprates, and BiS2-based layered superconductors.
Abstract
Since the discovery of superconductivity in a high-entropy alloy (HEA) Ti-Zr-Nb-Hf-Ta in 2014, the community of superconductor science has explored new HEA superconductors to find the merit of the HEA states on superconducting properties. Since 2018, we have developed HEA-type compounds as superconductors or thermoelectric materials. As well known, compounds like intermetallic compounds or layered compounds are composed of multi crystallographic sites. In a HEA-type compounds, one or more sites are alloyed and total mixing entropy satisfies with the criterion of HEA. Herein, we summarize the synthesis methods, the crystal structural variation and superconducting properties of the HEA-type compounds, which include NaCl-type metal tellurides, CuAl2-type transition metal zirconides, high-Tc cuprates, and BiS2-based layered superconductors. The effects of the introduction of a HEA site in various kinds of complicated compounds are discussed from the structural-dimensionality viewpoint.

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Citations
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Superconductivity at 55 K in Iron-Based F-Doped Layered Quaternary Compound Sm[O1-xFx]FeAs

TL;DR: The O1-xFx FeAs as discussed by the authorsx [O1-XFx ] FeAs,与在 55.0K 的发作抵抗力转变温度
Journal ArticleDOI

Anomalous broadening of specific heat jump at T c in high-entropy-alloy-type superconductor TrZr2

TL;DR: In this article, a broadening of specific heat jump near a superconducting transition tempreature (Tc) in transition-metal zirconides (TrZr2) with different mixing entropy (ΔSmix) at the Tr site is reported.
Journal ArticleDOI

Robustness of superconductivity to external pressure in high-entropy-alloy-type metal telluride AgInSnPbBiTe5

TL;DR: In this article , the authors investigated the crystal and electronic structure, and the robustness of superconducting states in a HEA-type metal telluride (MTe; M = Ag, In, Sn, Pb, Bi) under high pressure, and compared with the pressure effects for a middle entropy system (AgPbBiTe3) and a reference system of PbTe.
Journal ArticleDOI

Fabrication of high-entropy REBa<sub>2</sub>Cu<sub>3</sub>O<sub>7</sub>−δ thin films by pulsed laser deposition

TL;DR: In this article , thin films of RE Ba 2 Cu 3 O 7− δ (RE 123, RE : rare earth) having a high-entropy (HE) RE site were successfully fabricated by the pulsed laser deposition method.
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Superconductivity of high-entropy-alloy-type transition-metal zirconide (Fe,Co,Ni,Cu,Ga)Zr2

TL;DR: In this article , a new high-entropy-alloy-type (HEA-type) superconductor (Fe,Co,Ni,Cu,Ga)Zr2 with a T c of 2.9 K was synthesized.
References
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Journal ArticleDOI

Possible high Tc superconductivity in the Ba-La-Cu-O system

TL;DR: In this paper, Ba−La−Cu−O system, with the composition BaxLa5−xCu5O5(3−y) have been prepared in polycrystalline form, and samples with x=1 and 0.75,y>0, annealed below 900°C under reducing conditions, consist of three phases, one of them a perovskite-like mixed-valent copper compound.
Journal ArticleDOI

Iron-Based Layered Superconductor La[O1-xFx]FeAs (x = 0.05−0.12) with Tc = 26 K

TL;DR: It is reported that a layered iron-based compound LaOFeAs undergoes superconducting transition under doping with F- ions at the O2- site and exhibits a trapezoid shape dependence on the F- content.
Journal ArticleDOI

Superconductivity at 93 K in a new mixed-phase Y-Ba-Cu-O compound system at ambient pressure

TL;DR: A stable and reproducible superconductivity transition between 80 and 93 K has been unambiguously observed both resistively and magnetically in a new Y-Ba-Cu-O compound system at ambient pressure.
Journal ArticleDOI

Superconductivity at 39 K in magnesium diboride

TL;DR: In this article, the authors reported the discovery of bulk superconductivity in magnesium diboride, MgB2, with a transition temperature of 39'K, which they believe to be the highest yet determined for a non-copper-oxide bulk superconductor.