Journal ArticleDOI
Synthesis and symmetry transformation in the perovskite compounds PbHfO3 and CdHfO3
P.D. Dernier,J. P. Remeika +1 more
TLDR
In this paper, the perovskite compounds PbHfO3 and CdHmO3 have been shown to undergo a series of structural phase transformations at high temperature X-ray diffraction experiments.About:
This article is published in Materials Research Bulletin.The article was published on 1975-03-01. It has received 20 citations till now. The article focuses on the topics: Perovskite (structure) & Orthorhombic crystal system.read more
Citations
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Antiferroelectrics: History, fundamentals, crystal chemistry, crystal structures, size effects, and applications
TL;DR: Antiferroelectric (AFE) materials are of great interest owing to their scientific richness and their utility in high energy density capacitors as discussed by the authors, and the characteristics of AFE and the phase transition of an AFE material are described.
Journal ArticleDOI
Field-induced antiferroelectric-ferroelectric phase transitions in the Pb0.98La0.02(Zr0.70Hf0.30)(1-x)TixO3 system
TL;DR: In this article, a phase transition between the antiferroelectric AFE (II) phase and the ferroelectric phase was investigated in the Pb0.98La0.02(Zr0.70Hf0.30)TixO3 system.
Journal ArticleDOI
Anomalous dielectric behaviour during the monoclinic to tetragonal phase transition in La(Nb0.9V0.1)O4
Di Zhou,Huan-Huan Guo,Maosen Fu,Xiao-Gang Yao,Huixing Lin,Wen-Feng Liu,Li-Xia Pang,Charanjeet Singh,Sergei V. Trukhanov,Sergei V. Trukhanov,Alex Trukhanov,Alex Trukhanov,Ian M. Reaney +12 more
TL;DR: In this article, an anomalous decrease in relative permittivity at TM-T is predicted from the Clausius-Mosotti relation and Shannon's additive rule, which has not previously been observed in linear dielectrics and may aid in the design of novel microwave dielectric composites.
Journal ArticleDOI
Symmetry-determined antiferroelectricity in PbZr O 3 , NaNb O 3 , and PbHf O 3
P. Tolédano,Dmitry D. Khalyavin +1 more
TL;DR: In this article, a theoretical analysis of the complex phase transitions in the perovskite compounds of antiferroelectric and ferroelastic phase transitions is presented, and the symmetry-breaking order parameters associated with the transitions in these compounds are determined.
Journal ArticleDOI
Crystallographic and optical study of PbHfO3 crystals
TL;DR: The use of birefringence imaging microscopy and high-resolution X-ray diffraction for determining the symmetries of the phases in PbHfO3 between room temperature and 870 K is detailed.
References
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Journal ArticleDOI
The crystal chemistry of the rare earth orthoferrites
Journal ArticleDOI
X-Ray and Neutron Diffraction Study of Antiferroelectric Lead Zirconate, PbZr O 3
TL;DR: The room-temperature structure of antiferroelectric lead zirconate, PbZr${\mathrm{O}}_{3}], has been studied by x-ray and neutron diffraction.
Journal ArticleDOI
Pressure and Temperature Dependence of the Dielectric Properties and Phase Transitions of the Antiferroelectric Perovskites: PbZr O 3 and PbHf O 3
TL;DR: In this paper, the authors showed that there are two independent low-frequency temperature-dependent lattice vibrational modes in PbZr${\mathrm{O}}_{3}$: a ferroelectric (FE) mode which determines the large polarizability and the Curie-Weiss behavior of the static dielectric constant in the paraelectric phase, and an AFE mode (probably a coupled mode) which causes the AFE transition.
Journal ArticleDOI
Phase Transitions in Antiferroelectric PbHf O 3
Gen Shirane,R. Pepinsky +1 more
TL;DR: In this article, it was shown that at room temperature PbHf${\mathrm{O}}_{3}$ has a tetragonal lattice of the perovskite type with $a=4.136, and the axial ratio was much closer to unity (0.997).
Journal ArticleDOI
The crystal structures of orthorhombic SmAlO3 and of trigonal NdAlO3
TL;DR: In this article, it was shown that with the orthorhombic → trigonal transition, the distortion of the rare earth polyhedron decreases, whereas that of the aluminum octahedron increases slightly.
Related Papers (5)
The origin of antiferroelectricity in PbZrO3
Alexander K. Tagantsev,Kaushik Vaideeswaran,Sergey Vakhrushev,Alexey Filimonov,R. G. Burkovsky,R. G. Burkovsky,A. P. Shaganov,Daria Andronikova,A. I. Rudskoy,Alfred Q. R. Baron,Hiroshi Uchiyama,Dmitry Chernyshov,Alexei Bosak,Z. Ujma,Krystian Roleder,Andrzej Majchrowski,Jae-Hyeon Ko,Nava Setter +17 more