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Journal ArticleDOI

Thermal decomposition kinetics of sorghum straw via thermogravimetric analysis.

TLDR
The thermal decomposition of sorghum straw was investigated by non-isothermal thermogravimetric analysis, where the determination of kinetic triplet (activation energy, pre-exponential factor, and reaction model), was the key objective.
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This article is published in Bioresource Technology.The article was published on 2017-12-01. It has received 185 citations till now. The article focuses on the topics: Enthalpy & Gibbs free energy.

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Pyrolysis characteristics and kinetic studies of horse manure using thermogravimetric analysis

TL;DR: In this article, a kinetic study of the pyrolysis process of horse manure is investigated through the use of thermogravimetric analyses and the results of the kinetic study can be used for modelling devolatilisation and designing thermochemical conversion processes.
Journal ArticleDOI

Discernment of synergism in pyrolysis of biomass blends using thermogravimetric analysis.

TL;DR: This study reports pyrolysis kinetics of biomass blends using isoconversional methods, viz.
Journal ArticleDOI

Effect of torrefaction on pinewood pyrolysis kinetics and thermal behavior using thermogravimetric analysis.

TL;DR: The results showed that the content of hemicellulose in biomass decreased while cellulose and lignin increased after torrefaction, and the C-O peaks of torrefied biomass was strengthened in FTIR spectrum and the crystallinity degree was enhanced according to XRD analysis.
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Combustion behaviors of spent mushroom substrate using TG-MS and TG-FTIR: Thermal conversion, kinetic, thermodynamic and emission analyses.

TL;DR: The high correlation coefficient of the fitting plots and similar activation energy calculated by various methods indicated that four suitable iso-conversional methods were used, pointing to SMS as a promising biofuel for power generation.
Journal ArticleDOI

Pyrolysis of banana leaves biomass: Physico-chemical characterization, thermal decomposition behavior, kinetic and thermodynamic analyses.

TL;DR: Results showed that average activation energy ranges between 70.75 and 92.12 kJ/mol for the studied isoconversional model-free methods, and pre-exponential factor obtained from Kissinger method was found to vary from 107 to 1033 s-1.
References
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Journal ArticleDOI

Characteristics of hemicellulose, cellulose and lignin pyrolysis

TL;DR: In this article, the pyrolysis characteristics of three main components (hemicellulose, cellulose and lignin) of biomass were investigated using, respectively, a thermogravimetric analyzer (TGA) with differential scanning calorimetry (DSC) detector and a pack bed.
Journal ArticleDOI

A New Method of Analyzing Thermogravimetric Data

TL;DR: In this paper, a new method of obtaining the kinetic parameters from thermogravimetric curves has been proposed, which is simple and applicable to reactions which can not be analyzed by other methods.
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ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data

TL;DR: In this article, the authors have developed recommendations for reliable evaluation of kinetic parameters (the activation energy, the preexponential factor, and the reaction model) from the data obtained by means of thermal analysis methods such as TGA, differential scanning calorimetry (DSC), and differential thermal analysis (DTA).
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Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to a phenolic plastic

TL;DR: In this article, a technique was devised for obtaining rate laws and kinetic parameters which describe the thermal degradation of plastics from TGA data, based on the inter-comparison of experiments which were performed at different linear rates of heating.
Journal ArticleDOI

A unified correlation for estimating hhv of solid, liquid and gaseous fuels

TL;DR: In this article, a unified correlation for computation of higher heating value (HHV) from elemental analysis of fuels is proposed, which has been derived using 225 data points and validated for additional 50 data points.
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