Journal ArticleDOI
Two tetraphenylethene-containing coordination polymers for reversible mechanochromism
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TLDR
Two fluorescent coordination polymers have been designed and synthesized from a tetraphenylethene (TPE) derivative that exhibit reversible mechanochromic luminescence with color changes visible to the naked-eye from blue to green-yellow by grinding or soaking in N,N-dimethylformamide (DMF) under UV irradiation.About:
This article is published in Chemical Communications.The article was published on 2017-06-27. It has received 48 citations till now. The article focuses on the topics: Mechanochromic luminescence & Derivative (chemistry).read more
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Recent advances in mechano-responsive luminescence of tetraphenylethylene derivatives with aggregation-induced emission properties
TL;DR: This review will focus on recent advances in MRL of TPE derivatives with AIE properties, including a brief history of mechano-responsive AIE-active materials, mechanistic studies on MRL, and a perspective on the possible opportunities and future challenges that exist in this research area.
Journal ArticleDOI
Tetraphenylethylene immobilized metal-organic frameworks: highly sensitive fluorescent sensor for the detection of Cr2O72- and nitroaromatic explosives
TL;DR: In this article, three luminescent MOFs (1,2,2-tetrakis(4-(pyridin-4-yl)phenyl)ethane (TPPE) with the π-electron-rich tetraphenylethylene (TPE) and aggregation induced emission feature is selected as functional ligand to construct the fluorescent metal-organic frameworks.
Journal ArticleDOI
Guest-Triggered Aggregation-Induced Emission in Silver Chalcogenolate Cluster Metal-Organic Frameworks.
Xiao-Hui Wu,Peng Luo,Zhong Wei,Yuanyuan Li,Ren-Wu Huang,Xi-Yan Dong,Kai Li,Shuang-Quan Zang,Ben Zhong Tang +8 more
TL;DR: A dual‐node 3D silver chalcogenolate cluster MOF is designed and synthesized, where the AIE ligand shows relatively flexible and rotatable conformations that exhibited not only intense but also guest molecule switched luminescent properties.
Journal ArticleDOI
In situ encapsulation of pyridine-substituted tetraphenylethene cations in metal–organic framework for the detection of antibiotics in aqueous medium
TL;DR: In this article, a simple luminescent MOF was synthesized by in situ encapsulation of cationic TPE-based guest TMPyPE into an anionic MOF, which exhibits high stability and strong fluorescence in water, and can selectively and sensitively detect nitrofuran antibiotics in aqueous medium.
Journal ArticleDOI
Reversible Mechanochromic Delayed Fluorescence in 2D Metal-Organic Micro/Nanosheets: Switching Singlet-Triplet States through Transformation between Exciplex and Excimer.
Yongsheng Yang,Yongsheng Yang,Xiao-Gang Yang,Xiaoyu Fang,Ke-Zhi Wang,Dongpeng Yan,Dongpeng Yan +6 more
TL;DR: This work not only develops new 2D micro/nanosheets as MCDF materials, but also supplies a singlet–triplet energy switching mechanism on their reversible mechanochromic process.
References
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Journal ArticleDOI
Single-crystal structure validation with the program PLATON
TL;DR: The results of a single-crystal structure determination when in CIF format can now be validated routinely by automatic procedures, and the concepts of validation and the classes of checks carried out by the program PLATON as part of the IUCr checkCIF facility are described.
Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
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Metal–Organic Frameworks for Separations
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Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials
Journal ArticleDOI
Flexible metal–organic frameworks
Andreas Schneemann,Volodymyr Bon,Inke Schwedler,Irena Senkovska,Stefan Kaskel,Roland A. Fischer +5 more
TL;DR: Advances in flexible and functional metal-organic frameworks (MOFs), also called soft porous crystals, are reviewed by covering the literature of the five years period 2009-2013 with reference to the early pertinent work since the late 1990s.
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