Journal ArticleDOI
Visible-Light-Mediated β-C-H gem-Difluoroallylation of Aldehydes and Cyclic Ketones through C-F Bond Cleavage of 1-Trifluoromethyl Alkenes.
Reads0
Chats0
TLDR
A mild and concise route to access the target compounds through the visible-light-mediated direct β-C-H gem-difluoroallylation of aliphatic aldehydes and cyclic ketones is reported.About:
This article is published in Organic Letters.The article was published on 2020-03-05. It has received 58 citations till now. The article focuses on the topics: Photoredox catalysis & Bond cleavage.read more
Citations
More filters
Journal ArticleDOI
Transition-metal-catalyzed C–H allylation reactions
TL;DR: This review aims to embrace all the aspects of transition-metal-promoted C–H allylation reactions and shows that they trigger the allylic selectivity of an unsaturated hydrocarbon under proper metal-ligand combination.
Journal ArticleDOI
Recent advance in the C–F bond functionalization of trifluoromethyl-containing compounds
TL;DR: In this paper, the authors systematically summarized the C-F bond functionalization of trifluoromethyl-based compounds, and their mechanisms were also discussed, and discussed the most challenging task to study the activation of the C -F bond in organic synthesis.
Journal ArticleDOI
α-Amino Acids and Peptides as Bifunctional Reagents: Carbocarboxylation of Activated Alkenes via Recycling CO2.
Li-Li Liao,Guang-Mei Cao,Yuan-Xu Jiang,Xing-Hao Jin,Xin-Long Hu,Jason J. Chruma,Jason J. Chruma,Guo-Quan Sun,Yong-Yuan Gui,Yong-Yuan Gui,Da-Gang Yu +10 more
TL;DR: In this article, α-AAs have been used as bifunctional reagents in the redox-neutral carbocarboxylation of alkenes, which is an efficient and sustainable system for organic synthesis, pharmaceutics and biochemistry.
Journal ArticleDOI
Chromium-Catalyzed Allylic Defluorinative Ketyl Olefin Coupling.
TL;DR: In this article, a chromium-catalyzed allylic defluorinative ketyl olefin coupling between aldehydes and α-trifluoromethyl alkenes was reported, which enabled the conversion of the formyl moiety in the presence of various easily reducible functionalities including ketone, organohalides, aziridine, sulfone, alkyne and unactivated alkene.
Journal ArticleDOI
Photoredox/Hydrogen Atom Transfer Cocatalyzed C-H Difluoroallylation of Amides, Ethers, and Alkyl Aldehydes.
TL;DR: In this paper, a method that combines hydrogen atom transfer and photoredox catalysis to achieve the dehydrogenative difluoroallylation of amides, ethers, and alkyl aldehydes is described.
References
More filters
Journal ArticleDOI
Synopsis of some recent tactical application of bioisosteres in drug design.
TL;DR: In this Perspective, some contemporary themes exploring the role of isosteres in drug design are sampled, with an emphasis placed on tactical applications designed to solve the kinds of problems that impinge on compound optimization and the long-term success of drug candidates.
Journal ArticleDOI
Photophysics, photochemistry and solar energy conversion with tris(bipyridyl)ruthenium(II) and its analogues
TL;DR: In this paper, the authors presented a method for the extraction of the structure of the LPI-ARTICLE-1982-012 (LPI-2012-012) abstract from the Web of Science Record.
Journal ArticleDOI
C-F bond activation in organic synthesis.
Hideki Amii,Kenji Uneyama +1 more
TL;DR: Organic fluorine compounds have received a great deal of interest and attention from the scientists involved in diverse fields of science and technology and not only C-F bond formation but also selective C-f bond activation have become current subjects of active investigation from the viewpoint of effective synthesis of fluoroorganic compounds.
Journal ArticleDOI
Synthetic applications of eosin Y in photoredox catalysis
Durga Prasad Hari,Burkhard König +1 more
TL;DR: The key photophysical properties of the dye are summarized and the recent synthetic applications in photoredox catalysis are summarized.
Journal ArticleDOI
Single-Layer Electroluminescent Devices and Photoinduced Hydrogen Production from an Ionic Iridium(III) Complex
Michael S. Lowry,Jonas I. Goldsmith,Jason D. Slinker,Richard Rohl,Robert A. Pascal,George G. Malliaras,Stefan Bernhard +6 more
TL;DR: In this paper, the electronic structure and diverse applications of a highly luminescent ionic transition metal complex, [Ir(dF(CF3)ppy)2(dtbbpy)](PF6), were reported.
Related Papers (5)
Recent advances in the synthesis and CF functionalization of gem-difluoroalkenes
Xuxue Zhang,Song Cao +1 more