Showing papers by "Cinzia Casiraghi published in 2021"

Viscoelastic surface electrode arrays to interface with viscoelastic tissues.

Abstract: Living tissues are non-linearly elastic materials that exhibit viscoelasticity and plasticity. Man-made, implantable bioelectronic arrays mainly rely on rigid or elastic encapsulation materials and stiff films of ductile metals that can be manipulated with microscopic precision to offer reliable electrical properties. In this study, we have engineered a surface microelectrode array that replaces the traditional encapsulation and conductive components with viscoelastic materials. Our array overcomes previous limitations in matching the stiffness and relaxation behaviour of soft biological tissues by using hydrogels as the outer layers. We have introduced a hydrogel-based conductor made from an ionically conductive alginate matrix enhanced with carbon nanomaterials, which provide electrical percolation even at low loading fractions. Our combination of conducting and insulating viscoelastic materials, with top-down manufacturing, allows for the fabrication of electrode arrays compatible with standard electrophysiology platforms. Our arrays intimately conform to the convoluted surface of the heart or brain cortex and offer promising bioengineering applications for recording and stimulation.

Dispersant-assisted liquid-phase exfoliation of 2D materials beyond graphene

Abstract: The extensive research on liquid-phase exfoliation (LPE) performed in the last 10 years has enabled a low cost and mass scalable approach to the successful production of a range of solution-processed 2-dimensional (2D) materials suitable for many applications, from composites to energy storage and printed electronics. However, direct LPE requires the use of specific solvents, which are typically toxic and expensive. Dispersant-assisted LPE allows us to overcome this problem by enabling production of solution processed 2D materials in a wider range of solvents, including water. This approach is based on the inclusion of an additive, typically an amphiphilic molecule, designed to interact with both the nanosheet and the solvent, enabling exfoliation and stabilization at the same time. This method has been extensively used for the LPE of graphene and has been discussed in many reviews, whilst little attention has been given to dispersant-assisted LPE of 2D materials beyond graphene. Considering the increasing number of 2D materials and their potential in many applications, from nanomedicine to energy storage and catalysis, this review focuses on the dispersant-assisted LPE of transition metal dichalcogenides (TMDs), hexagonal boron nitride (h-BN) and less studied 2D materials. We first provide an introduction to the fundamentals of LPE and the type of dispersants that have been used for the production of graphene, we then discuss each class of 2D material, providing an overview on the concentration and properties of the nanosheets obtained. Finally, a perspective is given on some of the challenges that need to be addressed in this field of research.

Gamma Radiation-Induced Oxidation, Doping, and Etching of Two-Dimensional MoS2 Crystals

Abstract: Two-dimensional (2D) MoS2 is a promising material for future electronic and optoelectronic applications 2D MoS2 devices have been shown to perform reliably under irradiation conditions relevant for a low Earth orbit However, a systematic investigation of the stability of 2D MoS2 crystals under high-dose gamma irradiation is still missing In this work, absorbed doses of up to 1000 kGy are administered to 2D MoS2 Radiation damage is monitored via optical microscopy and Raman, photoluminescence, and X-ray photoelectron spectroscopy techniques After irradiation with 500 kGy dose, p-doping of the monolayer MoS2 is observed and attributed to the adsorption of O2 onto created vacancies Extensive oxidation of the MoS2 crystal is attributed to reactions involving the products of adsorbate radiolysis Edge-selective radiolytic etching of the uppermost layer in 2D MoS2 is attributed to the high reactivity of active edge sites After irradiation with 1000 kGy, the monolayer MoS2 crystals appear to be completely etched This holistic study reveals the previously unreported effects of high-dose gamma irradiation on the physical and chemical properties of 2D MoS2 Consequently, it demonstrates that radiation shielding, adsorbate concentrations, and required device lifetimes must be carefully considered, if devices incorporating 2D MoS2 are intended for use in high-dose radiation environments

Enhanced liquid phase exfoliation of graphene in water using an insoluble bis-pyrene stabiliser

Abstract: Stabilisers, such as surfactants, polymers and polyaromatic molecules, offer an effective way to produce graphene dispersions in water by Liquid Phase Exfoliation (LPE) without degrading the properties of graphene. In particular, pyrene derivatives provide better exfoliation efficiency than traditional surfactants and polymers. A stabiliser is expected to be relatively soluble in order to disperse hydrophobic graphene in water. Here, we show that exfoliation can also be achieved with insoluble pyrene stabilisers if appropriately designed. In particular, bis-pyrene stabilisers (BPSs) functionalised with pyrrolidine provide a higher exfoliation efficiency and percentage of single layers compared to traditional pyrene derivatives under the same experimental conditions. This is attributed to the enhanced interactions between BPS and graphene, provided by the presence of two pyrene binding groups. This approach is therefore attractive not only to produce highly concentrated graphene, but also to use graphene to disperse insoluble molecules in water. The enhanced adsorption of BPS on graphene, however, is reflected in higher toxicity towards human epithelial bronchial immortalized cells, limiting the use of this material for biomedical applications.

Inkjet-printed low-dimensional materials-based complementary electronic circuits on paper

Abstract: Complementary electronics has represented the corner stone of the digital era, and silicon technology has enabled this accomplishment. At the dawn of the flexible and wearable electronics age, the seek for new materials enabling the integration of complementary metal-oxide semiconductor (CMOS) technology on flexible substrates, finds in low-dimensional materials (either 1D or 2D) extraordinary candidates. Here, we show that the main building blocks for digital electronics can be obtained by exploiting 2D materials like molybdenum disulfide, hexagonal boron nitride and 1D materials such as carbon nanotubes through the inkjet-printing technique. In particular, we show that the proposed approach enables the fabrication of logic gates and a basic sequential network on a flexible substrate such as paper, with a performance already comparable with mainstream organic technology.

In situ probing of the thermal treatment of h-BN towards exfoliation.

Abstract: Two-dimensional (2D) hexagonal boron nitride (h-BN) is becoming increasingly interesting for wider engineering applications. Thermal exfoliation is being suggested as a facile technology to produce large quantities of 2D h-BN. Further optimization of the process requires fundamental understanding of the exfoliation mechanism, which is hardly realized by ex situ techniques. In this study, in situ synchrotron x-ray powder diffraction experiments are conducted while heat treating bulk h-BN up to 1273 K. During the heating process, linear expansion of c-axis is observed and the contraction of a-axis up to around 750 K is consistent with previous research. However, a changing behavior from contraction to expansion in a-axis direction is newly observed when heating over 750 K. With the consideration of previous thermally oxidation studies, a hypothesis of thermal assisted exfoliation with oxygen interstitial and substitution of nitrogen at high temperature is proposed.

Real-time monitoring of crystallization from solution by using an interdigitated array electrode sensor

Abstract: Monitoring crystallization events in real-time is challenging but crucial for understanding the molecular dynamics associated with nucleation and crystal growth, some of nature's most ubiquitous phenomena. Recent observations have suggested that the traditional nucleation model, which describes the nucleus having already the final crystal structure, may not be valid. It appears that the molecular assembly can range during nucleation from crystalline to partially ordered to totally amorphous phases, and can change its structure during the crystallization process. Therefore, it is of critical importance to develop methods that are able to provide real-time monitoring of the molecular interactions with high temporal resolution. Here, we demonstrate that a simple and scalable approach based on interdigitated electrode array sensors (IESs) is able to provide insights on the dynamics of the crystallization process with a temporal resolution of 15 ms.

Flexible printed articles

Abstract: One example of a flexible printed article includes a non-conductive, graphene oxide membrane base substrate; and an electronic component positioned on the non- conductive, graphene oxide membrane base substrate. An example method for generating this example of the flexible printed article includes inkjet printing a conductive ink directly on the non-conductive graphene oxide membrane base substrate.

Hybrid MoS2/PEDOT:PSS transporting layers for interface engineering of nanoplatelet-based light-emitting diodes

Abstract: Colloidal semiconductor nanoplatelets (NPLs) are a subgroup of quantum confined materials that have recently emerged as promising active materials for solution processed light-emitting diodes (LEDs) thanks to their peculiar structural and electronic properties as well as their reduced dimensionality. Nowadays, the conventional structure for NPL-based LEDs makes use of poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) as a hole transporting layer (HTL). This is a well-known conjugated conductive polymer because it leads to high LED efficiency, though it has limited stability in air due to its intrinsic acidity and hygroscopicity. Here, we develop a nanocomposite aqueous ink, obtained by blending commercial PEDOT:PSS with water-based, stable and highly concentrated molybdenum disulfide (MoS2) nanosheets, obtained via liquid phase exfoliation (LPE), which is suitable as a HTL for solution processed NPL-based LEDs. We demonstrate that the MoS2 additive effectively works as a performance booster in unpackaged devices, thereby prolonging the lifetime up to 1000 hours under ambient conditions. Moreover, the addition of MoS2 induces a modification of the anode interface properties, including a change in the work function and a significant enhancement of the permittivity of the HTL.