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Showing papers by "Hikaru Yabuta published in 2006"


Journal ArticleDOI
15 Dec 2006-Science
TL;DR: The Stardust spacecraft collected thousands of particles from comet 81P/Wild 2 and returned them to Earth for laboratory study, and preliminary examination shows that the nonvolatile portion of the comet is an unequilibrated assortment of materials that have both presolar and solar system origin.
Abstract: The Stardust spacecraft collected thousands of particles from comet 81P/Wild 2 and returned them to Earth for laboratory study. The preliminary examination of these samples shows that the nonvolatile portion of the comet is an unequilibrated assortment of materials that have both presolar and solar system origin. The comet contains an abundance of silicate grains that are much larger than predictions of interstellar grain models, and many of these are high-temperature minerals that appear to have formed in the inner regions of the solar nebula. Their presence in a comet proves that the formation of the solar system included mixing on the grandest scales.

886 citations


Journal ArticleDOI
15 Dec 2006-Science
TL;DR: The presence of deuterium and nitrogen-15 excesses suggest that some organics have an interstellar/protostellar heritage and a diverse suite of organic compounds is present and identifiable within the returned samples.
Abstract: Organics found in comet 81P/Wild 2 samples show a heterogeneous and unequilibrated distribution in abundance and composition. Some organics are similar, but not identical, to those in interplanetary dust particles and carbonaceous meteorites. A class of aromatic-poor organic material is also present. The organics are rich in oxygen and nitrogen compared with meteoritic organics. Aromatic compounds are present, but the samples tend to be relatively poorer in aromatics than are meteorites and interplanetary dust particles. The presence of deuterium and nitrogen-15 excesses suggest that some organics have an interstellar/protostellar heritage. Although the variable extent of modification of these materials by impact capture is not yet fully constrained, a diverse suite of organic compounds is present and identifiable within the returned samples.

547 citations


Journal ArticleDOI
TL;DR: It is suggested that, in a soil with a higher OC content, the HA can serve as more effective carrier of PCOPs from the soil to an aquatic environment when the larger quantities of PCops that are partitioned into the HA are able to dissolve in the aqueous phase.
Abstract: To elucidate the role of a soil humic acid (HA) in the transport of polychlorinated organic pollutants (PCOPs), such as polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans and coplanar-polychlorinated biphenyls, their partition coefficients (K doc) into an HA were compared with their adsorption coefficients (K OC) for a soil with a higher organic carbon (OC) content. The soil sample (ando soil) used in the present study was collected in the same location as the HA. The log K doc values were positively correlated with logarithm of octanol-water partition coefficients (log K OW) of the PCOPs, indicating that the partitioning of PCOPs into the HA was mainly due to hydrophobic interactions. However, the correlation between log K doc and log K OC was negative. This can be attributed to the enhanced water solubility of the PCOPs as the result of the dissolved organic matter from the soil. That is, when the more hydrophobic PCOPs with higher log K OW values are partitioned into the HA, then the larg...

16 citations