We present a review of current research on the optical properties of ZnO nanostructures. We provide a brief introduction to different fabrication methods for various ZnO nanostructures and some general guidelines on how fabrication parameters (temperature, vapor-phase versus solution-phase deposition, etc.) affect their properties. A detailed discussion of photoluminescence, both in the UV region and in the visible spectral range, is provided. In addition, different gain (excitonic versus electron hole plasma) and feedback (random lasing versus individual nanostructures functioning as Fabry-Perot resonators) mechanisms for achieving stimulated emission are described. The factors affecting the achievement of stimulated emission are discussed, and the results of time-resolved studies of stimulated emission are summarized. Then, results of nonlinear optical studies, such as second-harmonic generation, are presented. Optical properties of doped ZnO nanostructures are also discussed, along with a concluding outlook for research into the optical properties of ZnO.

Optical properties of ZnO nanostructures.

ZnO nanostructures for optoelectronics: Material properties and device applications

Localized fluid flow measurements with an He-Ne laser spectrometer

We analyze theoretically the optical properties of ideal semiconductor crystallites so small that they show quantum confinement in all three dimensions [quantum dots (QD's)]. In the limit of a QD much smaller than the bulk exciton size, the linear spectrum will be a series of lines, and we consider the phonon broadening of these lines. The lowest interband transition will saturate like a two-level system, without exchange and Coulomb screening. Depending on the broadening, the absorption and the changes in absorption and refractive index resulting from saturation can become very large, and the local-field effects can become so strong as to give optical bistability without external feedback. The small QD limit is more readily achieved with narrow-band-gap semiconductors.

Theory of the linear and nonlinear optical properties of semiconductor microcrystallites

Instabilities in semiconductor heterostructure growth can be exploited for the self-organized formation of nanostructures, allowing for carrier confinement in all three spatial dimensions. Beside the description of various growth modes, the experimental characterization of structural properties, such as size and shape, chemical composition, and strain distribution is presented. The authors discuss the calculation of strain fields, which play an important role in the formation of such nanostructures and also influence their structural and optoelectronic properties. Several specific materials systems are surveyed together with important applications.

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Structural properties of self-organized semiconductor nanostructures

InAs self-organized quantum dots inserted in InGaAs quantum well have been grown on GaAs substrates by molecular beam epitaxy. The lateral size of the InAs islands has been found to be approximately 1.5 times larger as compared to the InAs/GaAs case, whereas the island heights and surface densities were close in both cases. The quantum dot emission wavelength can be controllably changed from 1.1 to 1.3 μm by varying the composition of the InGaAs quantum well matrix. Photoluminescence at 1.33 μm from vertical optical microcavities containing the InAs/InGaAs quantum dot array was demonstrated.

InAs/InGaAs quantum dot structures on GaAs substrates emitting at 1.3 μm

Temperature invariant output slope efficiency and threshold current (T0=∞) in the temperature range of 5–75 °C have been measured for 1.3 μm p-doped self-organized quantum dot lasers. Similar undoped quantum dot lasers exhibit T0=69K in the same temperature range. A self-consistent model has been employed to calculate the various radiative and nonradiative current components in p-doped and undoped lasers and to analyze the measured data. It is observed that Auger recombination in the dots plays an important role in determining the threshold current of the p-doped lasers.

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The role of Auger recombination in the temperature-dependent output characteristics (T0=∞) of p-doped 1.3 μm quantum dot lasers

We report on GaAs-based broad area (100 µm) 1.3 µm quantum dot (QD) lasers with high CW output power (5 W) and wall-plug efficiency (56%). The reliability of the devices has been demonstrated beyond 3000 h of CW operation at 0.9 W and 40 °C heat sink temperature with 2% degradation in performance. P-doped QD lasers with a temperature-insensitive threshold current (T0 > 650 K) and differential efficiency (T1 = infinity) up to 80 °C have been realized.

http://iopscience.iop.org/article/10.1088/0268-1242/20/5/002/pdf

High power temperature-insensitive 1.3 µm InAs/InGaAs/GaAs quantum dot lasers

By inserting stacked sheets of nominally 0.7 monolayer CdSe into a ZnSe matrix we create a region with strong resonant excitonic absorption. This leads to an enhancement of the refractive index on the low-energy side of the absorption peak. Efficient waveguiding can thus be achieved without increasing the average refractive index of the active layer with respect to the cladding. Processed high-resolution transmission electron microscopy images show that the CdSe insertions form Cd-rich two-dimensional (Cd, Zn)Se islands with lateral sizes of about 5 nm. The islands act as quantum dots with a three-dimensional confinement for excitons. Zero-phonon gain is observed in the spectral range of excitonic and biexcitonic waveguiding. At high excitation densities excitonic gain is suppressed due to the population of the quantum dots with biexcitons.

Gain studies of (Cd, Zn)Se quantum islands in a ZnSe matrix

Single-mode vertical-cavity surface-emitting lasers based on dense arrays of stacked submonolayer grown InGaAs quantum dots, emitting near 980nm, demonstrate a modulation bandwidth of 10.5GHz. A low threshold current of 170μA, high differential efficiency of 0.53W∕A, and high modulation current efficiency factor of 14GHz∕mA are realized from a 1μm oxide aperture single-mode device with a side mode suppression ratio of >40dB and peak output power of >1mW. The lasers are also suitable for high temperature operation.

Igor Krestnikov

Papers

InAs/InGaAs quantum dot structures on GaAs substrates emitting at 1.3 μm

The role of Auger recombination in the temperature-dependent output characteristics (T0=∞) of p-doped 1.3 μm quantum dot lasers

High power temperature-insensitive 1.3 µm InAs/InGaAs/GaAs quantum dot lasers

Gain studies of (Cd, Zn)Se quantum islands in a ZnSe matrix

Single-mode submonolayer quantum-dot vertical-cavity surface-emitting lasers with high modulation bandwidth