Martin Lutz

TL;DR: In this article, the photophysical properties (UV−vis absorption/emission, quantum yield, lifetime of emission) were analyzed using a range of standard spectroscopic and spectrometric techniques.

TL;DR: In this paper, the Gibbs free energy of activation of the flipping movement was found to be around 56 kJ/mol in all cases, however, the activation enthalpy and entropy differed considerably.

TL;DR: The immobilization strategy is limited to applications below 1.4 V vs normal hydrogen electrode (NHE) as oxidation of the pyrene backbone is evident at higher potentials.

TL;DR: A bidentate ligand with an integrated anion receptor forms dimeric rhodium complexes that become monomeric upon binding acetate guest, which is the basis for effector responsive hydroformylation catalysis.

TL;DR: In this article, the synthesis and resolution of chiral phenoxaphosphane 3, with the stereogenic center at the phosphorus atom, was described, and the absolute configuration of enantiopure phosphanes 3a,b was assigned unequivocally by means of X-ray crystal structure determination for complex 9a and by combination of NOE(1H-1H)/COSY- (1H,1H) spectroscopy and DFT calculations for complexes 7a, b, which in both cases led to identical results.